1-methylsulfanyl-1-trifluoromethylsulfanyl-2-ethoxycarbonyl-2-phenylethene

Base Information

Chemical Name:1-methylsulfanyl-1-trifluoromethylsulfanyl-2-ethoxycarbonyl-2-phenylethene
CAS No.:1357503-97-9
Molecular Formula:C₁₃H₁₃F₃O₂S₂
Molecular Weight:322.372
Hs Code.:

Synonyms:1-methylsulfanyl-1-trifluoromethylsulfanyl-2-ethoxycarbonyl-2-phenylethene

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Chemical Property of 1-methylsulfanyl-1-trifluoromethylsulfanyl-2-ethoxycarbonyl-2-phenylethene

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Technology Process of 1-methylsulfanyl-1-trifluoromethylsulfanyl-2-ethoxycarbonyl-2-phenylethene

There total 2 articles about 1-methylsulfanyl-1-trifluoromethylsulfanyl-2-ethoxycarbonyl-2-phenylethene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

: 1357503-91-3
methyl 2-hydroxy-2-ethoxycatbonyl-2-phenylethanedithioate

: 81290-20-2
(trifluoromethyl)trimethylsilane

: 1357503-99-1
methyl 2-ethoxycarbonyl-2-phenyl-2-(trimethylsilyloxy)ethanedithioate

: 1357503-97-9
1-methylsulfanyl-1-trifluoromethylsulfanyl-2-ethoxycarbonyl-2-phenylethene

Guidance literature:: With tetramethylammonium fluoride; In tetrahydrofuran; at -20 - 20 ℃;
DOI:10.1016/j.jfluchem.2011.02.016

Reference yield:

: 22768-02-1
benzyl ethyl carbonate

: 1357503-99-1
methyl 2-ethoxycarbonyl-2-phenyl-2-(trimethylsilyloxy)ethanedithioate

: 1357503-97-9
1-methylsulfanyl-1-trifluoromethylsulfanyl-2-ethoxycarbonyl-2-phenylethene

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium; diisopropylamine / tetrahydrofuran; hexane / 0.33 h / -20 °C / Inert atmosphere

1.2: 1 h / -20 - -5 °C / Inert atmosphere

1.3: 4 h / 20 °C / Inert atmosphere

2.1: tetramethylammonium fluoride / tetrahydrofuran / -20 - 20 °C

With n-butyllithium; tetramethylammonium fluoride; diisopropylamine; In tetrahydrofuran; hexane;
DOI:10.1016/j.jfluchem.2011.02.016