<4R-<4R<αR(S),γS>>>-γ-<(4-methoxyphenyl)methoxy>-2,2-dimethyl-α-(1-methyl-2-propenyl)-1,3-dioxolane-4-propanol

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Chemical Name:<4R-<4R*<αR*(S*),γS*>>>-γ-<(4-methoxyphenyl)methoxy>-2,2-dimethyl-α-(1-methyl-2-propenyl)-1,3-dioxolane-4-propanol
CAS No.:152453-73-1
Molecular Formula:C₂₀H₃₀O₅
Molecular Weight:350.455
Hs Code.:

Synonyms:<4R-<4R*<αR*(S*),γS*>>>-γ-<(4-methoxyphenyl)methoxy>-2,2-dimethyl-α-(1-methyl-2-propenyl)-1,3-dioxolane-4-propanol

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Chemical Property of <4R-<4R*<αR*(S*),γS*>>>-γ-<(4-methoxyphenyl)methoxy>-2,2-dimethyl-α-(1-methyl-2-propenyl)-1,3-dioxolane-4-propanol

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Technology Process of <4R-<4R*<αR*(S*),γS*>>>-γ-<(4-methoxyphenyl)methoxy>-2,2-dimethyl-α-(1-methyl-2-propenyl)-1,3-dioxolane-4-propanol

There total 4 articles about <4R-<4R*<αR*(S*),γS*>>>-γ-<(4-methoxyphenyl)methoxy>-2,2-dimethyl-α-(1-methyl-2-propenyl)-1,3-dioxolane-4-propanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 67320-20-1,83692-41-5,94292-91-8,64722-95-8
1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-3,3-bis-ethylsulfanyl-propan-1-ol

: 152453-73-1
<4R-<4R*<αR*(S*),γS*>>>-γ-<(4-methoxyphenyl)methoxy>-2,2-dimethyl-α-(1-methyl-2-propenyl)-1,3-dioxolane-4-propanol

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) NaH / 1.) DMF, RT, 3 h, 2.) DMF, RT, 45 min

2: 77 percent / CaCO₃, HgCl₂ / acetonitrile; H₂O / 0.83 h / Ambient temperature

3: 1.) BF₃*Et₂O, 2.) a) 3 M aq. NaOH, b) 30percent aq. H₂O₂ / 1.) THF, hexane, -78 deg C, 1.5 h, 2.) THF, hexane, a) from -78 deg C to RT

With sodium hydroxide; boron trifluoride diethyl etherate; dihydrogen peroxide; sodium hydride; calcium carbonate; mercury dichloride; In water; acetonitrile;
DOI:10.1021/ja00136a025

Reference yield:

: 2746-25-0
p-Methoxybenzyl bromide

: 152453-73-1
<4R-<4R*<αR*(S*),γS*>>>-γ-<(4-methoxyphenyl)methoxy>-2,2-dimethyl-α-(1-methyl-2-propenyl)-1,3-dioxolane-4-propanol

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) NaH / 1.) DMF, RT, 3 h, 2.) DMF, RT, 45 min

2: 77 percent / CaCO₃, HgCl₂ / acetonitrile; H₂O / 0.83 h / Ambient temperature

3: 1.) BF₃*Et₂O, 2.) a) 3 M aq. NaOH, b) 30percent aq. H₂O₂ / 1.) THF, hexane, -78 deg C, 1.5 h, 2.) THF, hexane, a) from -78 deg C to RT

With sodium hydroxide; boron trifluoride diethyl etherate; dihydrogen peroxide; sodium hydride; calcium carbonate; mercury dichloride; In water; acetonitrile;
DOI:10.1021/ja00136a025

Reference yield:

: 152453-71-9
(1'S,4R)-4-(3',3'-bisethylthio-1'-p-methoxybenzyloxypropyl)-2,2-dimethyl-1,3-dioxolane

: 152453-73-1
<4R-<4R*<αR*(S*),γS*>>>-γ-<(4-methoxyphenyl)methoxy>-2,2-dimethyl-α-(1-methyl-2-propenyl)-1,3-dioxolane-4-propanol

Guidance literature:: Multi-step reaction with 2 steps

1: 77 percent / CaCO₃, HgCl₂ / acetonitrile; H₂O / 0.83 h / Ambient temperature

2: 1.) BF₃*Et₂O, 2.) a) 3 M aq. NaOH, b) 30percent aq. H₂O₂ / 1.) THF, hexane, -78 deg C, 1.5 h, 2.) THF, hexane, a) from -78 deg C to RT

With sodium hydroxide; boron trifluoride diethyl etherate; dihydrogen peroxide; calcium carbonate; mercury dichloride; In water; acetonitrile;
DOI:10.1021/ja00136a025