dihydroxyacetone phosphate ethyl hemiacetal dimer barium

Base Information

• Chemical Name: dihydroxyacetone phosphate ethyl hemiacetal dimer barium
• CAS No.: 113125-24-9
• Molecular Formula: C10H22 O12 P2 . 3/2 Ba
• Molecular Weight: 666.853
• Mol file: 113125-24-9.mol

Synonyms:dihydroxyacetone phosphate ethyl hemiacetal dimer barium

Chemical Property of dihydroxyacetone phosphate ethyl hemiacetal dimer barium

Chemical Property:

• PSA: 201.38000
• LogP: 1.47020

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of dihydroxyacetone phosphate ethyl hemiacetal dimer barium

There total 2 articles about dihydroxyacetone phosphate ethyl hemiacetal dimer barium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,5-diethoxy-p-dioxane-2,5-dimethanol-O-21-O-51-bisphosphate (47325-43-9) → barium salt of 2,5-bis(phosphonooxymethyl)-2,5-diethoxy-1,4-dioxane (113125-24-9)

Guidance literature:

With sodium hydroxide; barium(II) chloride; Yield given; 1.) H₂O, 4 deg C, 10 h, 2.) EtOH, O deg C, 3 h;

DOI:10.1016/S0040-4039(00)95380-2

Reference yield:

2,5-diethoxy-2,5-bis(hydroxymethyl)-1,4-dioxane (18294-29-6) + diphenyl-N,N-diethylphosphoramidite (14747-96-7) → dimeric dihydroxyacetone phosphate ethyl hemiacetal barium salt (113125-24-9)

Guidance literature:

With dihydrogen peroxide; Multistep reaction; 1) THF, r.t., 2) r.t.;

DOI:10.1016/S0040-4020(01)81796-8

Reference yield: 80.0%

barium salt of 2,5-bis(phosphonooxymethyl)-2,5-diethoxy-1,4-dioxane (113125-24-9) → dihydroxyacetone phosphate (57-04-5)

Guidance literature:

With DOWEX 50 WX 8H⁽¹⁺⁾; In water; at 65 ℃; for 4h; pH = 1.0;

DOI:10.1016/S0040-4039(00)95380-2

upstream raw materials:

2,5-diethoxy-2,5-bis(hydroxymethyl)-1,4-dioxane

diphenyl-N,N-diethylphosphoramidite

2,5-diethoxy-p-dioxane-2,5-dimethanol-O-2¹-O-5¹-bisphosphate

Downstream raw materials:

dihydroxyacetone phosphate

Refernces

• 1、 Pederson,Esker,Wong. "An improved synthesis of dihydroxyacetone phosphate". . p. 2643 - 2648. Retrieved 2007/10/02.