14747-96-7

Basic information

• Product Name: diphenyl-N,N-diethylphosphoramidite
• Synonyms: diphenyl-N,N-diethylphosphoramidite
• CAS NO: 14747-96-7
• Molecular Weight: 289.314
• Mol File: 14747-96-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: diphenyl-N,N-diethylphosphoramidite(CAS DataBase Reference)
• NIST Chemistry Reference: diphenyl-N,N-diethylphosphoramidite(14747-96-7)
• EPA Substance Registry System: diphenyl-N,N-diethylphosphoramidite(14747-96-7)

Safety Data

• Hazardous Substances Data: 14747-96-7(Hazardous Substances Data)

Upstream product

• 54305-75-8 N,N-diethylaminodiiodophosphine 
• 139-02-6 sodium phenoxide 
• 2283-11-6 hexaethylphosphoric triamide 
• 108-95-2 phenol 
• 1069-08-5 diethylphosphoramidous dichloride 
• 14684-28-7 phenyl phosphorous tetraethyldiamide 
• 132958-38-4 tetrahexylcalix[4]resorcinarene 
• 74378-21-5 C-phenylcalix[4]resorcinarene 
• 5382-00-3 Diphenyl phosphorochloridite 
• 109-89-7 diethylamine 

Downstream Products

• 24102-75-8 phenyl diethylamidophenylphosphonite 
• 3577-87-5 diphenyl methyl phosphite 
• 113125-24-9 dimeric dihydroxyacetone phosphate ethyl hemiacetal barium salt 
• 7526-26-3 diphenyl methylphosphonate 
• 105751-11-9 H-Glu-Ser(PO₃Ph₂)-Leu-OH*CF₃CO₂H 
• 105751-09-5 Boc-Glu(OBzl)-Ser(PO₃Ph₂)-Leu-OBzl 
• 106111-03-9 Boc-Ser(PO₃Ph₂)-Leu-OBzl 
• 106128-52-3 Boc-Ser(PO₃Ph₂)-ONb 
• 105751-07-3 N^α-(t-butoxycarbonyl)-O-(diphenylphosphono)-L-serine 
• 135052-86-7 [(3aR,4S,6S,7R,7aS)-6-Methoxy-7-(4-methoxy-benzyloxy)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-4-ylmethyl]-phosphonic acid diphenyl ester 
• 135052-85-6 ((3aR,5S,5aR,8aS,8bR)-2,2,7,7-Tetramethyl-tetrahydro-bis[1,3]dioxolo[4,5-b;4',5'-d]pyran-5-ylmethyl)-phosphonic acid diphenyl ester 
• 1709-50-8 N,N-diethylbenzenesulfonamide 
• 7330-17-8 isopropyl diphenyl phosphite 
• 7434-44-8 phosphoric acid butyl ester-diphenyl ester 

Relevant articles and documents

Dismutation of arylene phosphorodiamidites: Specific features and aspects of preparative use

The dismutation of arylene phosphorodiamidites derived from the simplest phenols and naphthols and of their dibasic analogs was studied. The main regular trends of this process and the limits of its synthetic applicability were determined. Pleiades Publishing, Inc., 2006.

Cyclophosphorylation of polyphenols by diamidoarylphosphites

It was found that the cyclophosphorylation of polyphenols by diamidoarylphosphites proceeds via the rupture of only one P-N bond and one P-O bond, the second P-N bond remaining intact. It is supposed that the unusual lack of reactivity of the P-N bond is due to the spatial arrangement of the amido group with respect to the reaction site in phosphorylated intermediates 5.

Synthesis of Phosphonates: a Modified Arbuzov Procedure

Reactions of 6-iodogalactosides with either methyl or isopropyl diphenyl phosphite lead to diphenylphosphoryl derivatives; these can be converted by ester exchange into dibenzylphosphoryl derivatives, which are convenient precursors of carbohydrate phosphonic acids.