[(1,2,5,6-η)-cycloocta-1,5-diene]bis[triphenylphosphine-κP]rhodium(1+) perchlorate

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Chemical Name:[(1,2,5,6-η)-cycloocta-1,5-diene]bis[triphenylphosphine-κP]rhodium(1+) perchlorate
CAS No.:32799-30-7
Molecular Formula:C₄₄H₄₂P₂Rh*ClO₄
Molecular Weight:835.121
Hs Code.:

Synonyms:[(1,2,5,6-η)-cycloocta-1,5-diene]bis[triphenylphosphine-κP]rhodium(1+) perchlorate

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Chemical Property of [(1,2,5,6-η)-cycloocta-1,5-diene]bis[triphenylphosphine-κP]rhodium(1+) perchlorate

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Technology Process of [(1,2,5,6-η)-cycloocta-1,5-diene]bis[triphenylphosphine-κP]rhodium(1+) perchlorate

There total 3 articles about [(1,2,5,6-η)-cycloocta-1,5-diene]bis[triphenylphosphine-κP]rhodium(1+) perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 12092-47-6
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

: 32799-30-7
[(1,2,5,6-η)-cycloocta-1,5-diene]bis[triphenylphosphine-κP]rhodium(1+) perchlorate

Guidance literature:: With PPh₃, NaClO₄*H₂O; In acetone; byproducts: NaCl; PPh3 was added to the mixt. of Rh complex and NaClO4 in acetone, extra acetone was added, the mixt. was stirred for 5 min under N2 at 25°C; the solvent was evapd., CH2Cl2 was added, ppt. was filtered, the soln. was concd., ethanol was added, pptd. with ether, elem. anal.;
DOI:10.1016/S0020-1693(00)86576-7

Reference yield:

: 99243-78-4
(cyclooctadiene)bis(4-methylquinoline N-oxide)rhodium(I) perchlorate

: 32799-30-7
[(1,2,5,6-η)-cycloocta-1,5-diene]bis[triphenylphosphine-κP]rhodium(1+) perchlorate

Guidance literature:: With triphenylphosphine; In acetone; addn. of ligand to acetone soln. of complex;; concd. under vac., Et2O was added;;
DOI:10.1016/S0020-1693(00)84366-2