trans-Pd(COPh)I(PCy₃)2

Base Information

Chemical Name:trans-Pd(COPh)I(PCy₃)2
CAS No.:108818-38-8
Molecular Formula:C₄₃H₇₁IOP₂Pd
Molecular Weight:899.308
Hs Code.:

Synonyms:trans-Pd(COPh)I(PCy₃)2

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Chemical Property of trans-Pd(COPh)I(PCy₃)2

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Technology Process of trans-Pd(COPh)I(PCy₃)2

There total 2 articles about trans-Pd(COPh)I(PCy₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 108818-35-5
trans-[Pd(P(C₆H₁₁)3)2(C₆H₅)I]

: 108818-38-8
trans-Pd(COPh)I(PCy₃)2

Guidance literature:: With carbon monoxide; In dichloromethane; solvent was added under N2 to an autoclave containing Ph-complex; system was evacuated and 10 atm of CO was introduced; after stirring for 2 h at room temp. CO was purged, solvent was removed in vacuo and residue was washed by ether; recrystd. from CH2Cl2-ether; elem. anal., IR and NMR spectra;

Reference yield: 68.0%

: trans[iodobis(triphenylphosphine)phenylpalladium(II)]

: 1641-69-6
[13C]Carbon monoxide

: 108818-38-8
((C₆H₅)3P)2(⁽¹³⁾COC₆H₅)PdI

Guidance literature:: In dichloromethane; mixt. of Ph-complex with solvent in a Schlenk tube was evacuated and an atmospheric pressure of (13)CO was introduced; after stirring for 2 h at room temp. the CO gas was purged, the soln. was concd. to ca. 1 ml and Et2O was added; recrystd. CH2Cl2-Et2O; identified by IR spectra;

Reference yield:

: 108818-38-8
trans-Pd(COPh)I(PCy₃)2

: C₆H₅COPd(CO)(P(C₆H₁₁)3)2I

Guidance literature:: With carbon monoxide; In methanol; dichloromethane; reaction was carried out under CO pressure 20 atm at room temp.; not isolated, monitored by IR and NMR spectra;