(1'R,2'R,4R,5R)-2-{2'-[(E)-hex-1''-enyl]cyclopropyl}-4,5-bis(methoxydiphenylmethyl)-1,3,2-dioxaborolane

Base Information

Chemical Name:(1'R,2'R,4R,5R)-2-{2'-[(E)-hex-1''-enyl]cyclopropyl}-4,5-bis(methoxydiphenylmethyl)-1,3,2-dioxaborolane
CAS No.:1027355-56-1
Molecular Formula:C₃₉H₄₃BO₄
Molecular Weight:586.579
Hs Code.:

Synonyms:(1'R,2'R,4R,5R)-2-{2'-[(E)-hex-1''-enyl]cyclopropyl}-4,5-bis(methoxydiphenylmethyl)-1,3,2-dioxaborolane

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Chemical Property of (1'R,2'R,4R,5R)-2-{2'-[(E)-hex-1''-enyl]cyclopropyl}-4,5-bis(methoxydiphenylmethyl)-1,3,2-dioxaborolane

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Technology Process of (1'R,2'R,4R,5R)-2-{2'-[(E)-hex-1''-enyl]cyclopropyl}-4,5-bis(methoxydiphenylmethyl)-1,3,2-dioxaborolane

There total 3 articles about (1'R,2'R,4R,5R)-2-{2'-[(E)-hex-1''-enyl]cyclopropyl}-4,5-bis(methoxydiphenylmethyl)-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 203317-33-3
5-(pentane-1-sulfonyl)-1-phenyl-1H-1,2,3,4-tetrazole

: 321882-79-5
(1R,2R)-2-[(4R,5R)-4,5-Bis-(methoxy-diphenyl-methyl)-[1,3,2]dioxaborolan-2-yl]-cyclopropanecarbaldehyde

: 1027355-56-1
(1'R,2'R,4R,5R)-2-{2'-[(E)-hex-1''-enyl]cyclopropyl}-4,5-bis(methoxydiphenylmethyl)-1,3,2-dioxaborolane

Guidance literature:: 5-(pentane-1-sulfonyl)-1-phenyl-1H-1,2,3,4-tetrazole; With potassium hexamethylsilazane; In 1,2-dimethoxyethane; at -60 ℃; for 0.0833333h;

(1R,2R)-2-[(4R,5R)-4,5-Bis-(methoxy-diphenyl-methyl)-[1,3,2]dioxaborolan-2-yl]-cyclopropanecarbaldehyde; In 1,2-dimethoxyethane; at -60 ℃; for 0.166667h;
DOI:10.1055/s-2008-1042918

Reference yield:

: 592-41-6,25067-06-5
1-hexene

: 615574-37-3
(4R,5R)-4,5-Bis-(methoxy-diphenyl-methyl)-2-((1R,2R)-2-vinyl-cyclopropyl)-[1,3,2]dioxaborolane

: (1'R,2'R,4R,5R)-2-{2'-[(Z)-hex-1''-enyl]cyclopropyl}-4,5-bis(methoxydiphenylmethyl)-1,3,2-dioxaborolane

: 1027355-56-1
(1'R,2'R,4R,5R)-2-{2'-[(E)-hex-1''-enyl]cyclopropyl}-4,5-bis(methoxydiphenylmethyl)-1,3,2-dioxaborolane

Guidance literature:: With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; at 40 ℃; for 96h;
DOI:10.1055/s-2008-1042918

Reference yield:

: 21406-61-1
pentyltriphenylphosphonium bromide

: 321882-79-5
(1R,2R)-2-[(4R,5R)-4,5-Bis-(methoxy-diphenyl-methyl)-[1,3,2]dioxaborolan-2-yl]-cyclopropanecarbaldehyde

: (1'R,2'R,4R,5R)-2-{2'-[(Z)-hex-1''-enyl]cyclopropyl}-4,5-bis(methoxydiphenylmethyl)-1,3,2-dioxaborolane

: 1027355-56-1
(1'R,2'R,4R,5R)-2-{2'-[(E)-hex-1''-enyl]cyclopropyl}-4,5-bis(methoxydiphenylmethyl)-1,3,2-dioxaborolane

Guidance literature:: pentyltriphenylphosphonium bromide; With n-butyllithium; lithium bromide; In tetrahydrofuran; diethyl ether; at 20 ℃; for 0.333333h;

(1R,2R)-2-[(4R,5R)-4,5-Bis-(methoxy-diphenyl-methyl)-[1,3,2]dioxaborolan-2-yl]-cyclopropanecarbaldehyde; In tetrahydrofuran; diethyl ether; at -78 - -30 ℃; for 0.333333h;

With n-butyllithium; potassium tert-butylate; hydrochloric acid diethyl ether; In tetrahydrofuran; diethyl ether; Further stages;
DOI:10.1055/s-2008-1042918