hexacarbonyl-(μ-di-tert-butylphosphido)-(μ-dicyclohexylphosphido)diiron

Base Information

Chemical Name:hexacarbonyl-(μ-di-tert-butylphosphido)-(μ-dicyclohexylphosphido)diiron
CAS No.:140633-99-4
Molecular Formula:C₂₆H₄₀Fe₂O₆P₂
Molecular Weight:622.242
Hs Code.:

Synonyms:hexacarbonyl-(μ-di-tert-butylphosphido)-(μ-dicyclohexylphosphido)diiron

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Chemical Property of hexacarbonyl-(μ-di-tert-butylphosphido)-(μ-dicyclohexylphosphido)diiron

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Technology Process of hexacarbonyl-(μ-di-tert-butylphosphido)-(μ-dicyclohexylphosphido)diiron

There total 2 articles about hexacarbonyl-(μ-di-tert-butylphosphido)-(μ-dicyclohexylphosphido)diiron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 13463-40-6,37220-42-1
iron pentacarbonyl

: Collman's reagent

: 13716-10-4
di(tert-butyl)chlorophosphine

: 16523-54-9
chlorodicyclohexylphosphane

: 140633-99-4
hexacarbonyl-(μ-di-tert-butylphosphido)-(μ-dicyclohexylphosphido)diiron

: {Fe₂(CO)6(P(C₆H₁₁)2)2}

Guidance literature:: In tetrahydrofuran; Irradiation (UV/VIS); a photoreactor is charged with Na2(Fe(CO)4) in THF, addn. of P(Bu-t)2Cl, stirring for 2 h, addn. of Fe(CO)5, stirring for 24 h, photolyzing until gas evolution is finished, addn. of P(Cy)2Cl, stirring for 12 h; removal of solvent under vac., column chromy. (hexane/benzene);

Reference yield: 55.0%

: 138899-38-4
Na⁽¹⁺⁾*Fe₂⁽¹⁺⁾*7CO*2P(C(CH₃)3)2^(1-) = Na{Fe₂(CO)7(P(C₄H₉)2)2}

: 16523-54-9
chlorodicyclohexylphosphane

: 140633-99-4
hexacarbonyl-(μ-di-tert-butylphosphido)-(μ-dicyclohexylphosphido)diiron

Guidance literature:: In tetrahydrofuran; byproducts: NaCl; Ar atmosphere; refluxing (3 h); filtration, evapn. (vac.), dissolution (THF), addn. of 2-propanol, removal of THF (vac.), filtration, washing (MeOH); elem. anal.;

Reference yield: 100.0%

: 140633-99-4
hexacarbonyl-(μ-di-tert-butylphosphido)-(μ-dicyclohexylphosphido)diiron

: 140657-01-8
pentacarbonyl-(μ-di-tert-butylphosphido)-(μ-dicyclohexylphosphido)diiron

Guidance literature:: In n-heptane; byproducts: CO; Irradiation (UV/VIS); a photoreactor is charged with Fe-complex in heptane, photolyzation for 90 min under Ar; isolation of product is described in: Walther, B., Hartung, H., Reinhold, J.; Jones, P. G., Boettcher, H.C., Baumeister, U., Krug, A. Chem. Ber. 1992, 125 1379;