2-azidoethyl 2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside

Base Information

Chemical Name:2-azidoethyl 2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside
CAS No.:1380489-89-3
Molecular Formula:C₂₄H₂₇N₃O₇
Molecular Weight:469.494
Hs Code.:

Synonyms:2-azidoethyl 2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside

Suppliers and Price of 2-azidoethyl 2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-azidoethyl 2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside

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Technology Process of 2-azidoethyl 2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside

There total 1 articles about 2-azidoethyl 2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 1517-05-1
2-azidoethanol

: 158716-09-7
phenyl 2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-1-thio-α-D-mannopyranoside

: 1380489-89-3
2-azidoethyl 2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside

Guidance literature:: With N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -40 - 30 ℃; for 1h; Molecular sieve; Inert atmosphere;
DOI:10.1002/ejoc.201200041

Reference yield: 90.0%

: 1380489-89-3
2-azidoethyl 2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside

: 1238337-18-2
2-azidoethyl 3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside

Guidance literature:: 2-azidoethyl 2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside; With sodium methylate; In methanol; at 20 ℃; for 2h; Inert atmosphere;

In methanol; Inert atmosphere;
DOI:10.1002/ejoc.201200041

Reference yield:

: 1380489-89-3
2-azidoethyl 2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside

: 1380489-93-9
1-[2-((2,3-di-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl)-(1->2)-(3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranosyloxy))ethyl]-4-hydroxymethyl-1,2,3-triazole

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium methylate / methanol / 2 h / 20 °C / Inert atmosphere

1.2: Dowex 50WX₈-100 (H⁺) / Inert atmosphere

2.1: 1-benzenesulfinyl piperidine; trifluoromethylsulfonic anhydride; 2,4,6-tri-tert-butylpyrimidine / dichloromethane / -60 °C / Molecular sieve; Inert atmosphere

2.2: -78 °C / Molecular sieve; Inert atmosphere

3.1: copper(II) sulfate; sodium L-ascorbate / dichloromethane; water; tert-butyl alcohol / 20 °C / Inert atmosphere

With 1-benzenesulfinyl piperidine; trifluoromethylsulfonic anhydride; sodium methylate; copper(II) sulfate; sodium L-ascorbate; 2,4,6-tri-tert-butylpyrimidine; In methanol; dichloromethane; water; tert-butyl alcohol;
DOI:10.1002/ejoc.201200041