C₆₁H₈₅NO₁₉

Base Information

• Chemical Name: C₆₁H₈₅NO₁₉
• CAS No.: 1416780-06-7
• Molecular Formula: C₆₁H₈₅NO₁₉
• Molecular Weight: 1136.34
• Mol file: 1416780-06-7.mol

Synonyms:C₆₁H₈₅NO₁₉

Chemical Property of C₆₁H₈₅NO₁₉

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆₁H₈₅NO₁₉

There total 6 articles about C₆₁H₈₅NO₁₉ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.7%

C54H76O20 (1416779-87-7) + benzylamine (100-46-9) → C61H85NO19 (1416780-06-7)

Guidance literature:

With sodium cyanoborohydride; acetic acid; In methanol; at 20 ℃; for 3h; pH=Ca. 6; Inert atmosphere;

DOI:10.1021/jm301248y

Reference yield:

(2S,4aS,6aS,6bR,8aR,10S,12aS,12bR,14bR)-10-(((2R,3R,4S,5S,6S)-4,5-diacetoxy-6-(methoxycarbonyl)-3-(((2R,3R,4S,5S,6S)-3,4,5-triacetoxy-6-(methoxycarbonyl)tetrahydro-2H-pyran-2-yl)oxy)tetrahydro-2H-pyran-2-yl)oxy)-2,4a,6a,6b,9,9,12a-heptamethyl-13-oxo-1,2,3,4,4a,5,6,6a,6b,7,8,8a,9,10,11,12,12a,12b,13,14b-icosahydropicene-2-carboxylic acid (118342-92-0,118525-42-1) → C61H85NO19 (1416780-06-7)

Guidance literature:

Multi-step reaction with 4 steps

1: triethylamine / tetrahydrofuran / 0.5 h / -5 °C / Inert atmosphere

2: sodium tetrahydroborate / water / 4.5 h / 10 - 20 °C / Inert atmosphere

3: pyridinium chlorochromate / dichloromethane / 2 h / 0 - 20 °C / Inert atmosphere

4: acetic acid; sodium cyanoborohydride / methanol / 3 h / 20 °C / pH Ca_. 6 / Inert atmosphere

With sodium tetrahydroborate; sodium cyanoborohydride; acetic acid; triethylamine; pyridinium chlorochromate; In tetrahydrofuran; methanol; dichloromethane; water;

DOI:10.1021/jm301248y

Reference yield:

C54H78O20 (1416779-82-2) → C61H85NO19 (1416780-06-7)

Guidance literature:

Multi-step reaction with 2 steps

1: pyridinium chlorochromate / dichloromethane / 2 h / 0 - 20 °C / Inert atmosphere

2: acetic acid; sodium cyanoborohydride / methanol / 3 h / 20 °C / pH Ca_. 6 / Inert atmosphere

With sodium cyanoborohydride; acetic acid; pyridinium chlorochromate; In methanol; dichloromethane;

DOI:10.1021/jm301248y

upstream raw materials:

(2S,4aS,6aS,6bR,8aR,10S,12aS,12bR,14bR)-10-(((2R,3R,4S,5S,6S)-4,5-diacetoxy-6-(methoxycarbonyl)-3-(((2R,3R,4S,5S,6S)-3,4,5-triacetoxy-6-(methoxycarbonyl)tetrahydro-2H-pyran-2-yl)oxy)tetrahydro-2H-pyran-2-yl)oxy)-2,4a,6a,6b,9,9,12a-heptamethyl-13-oxo-1,2,3,4,4a,5,6,6a,6b,7,8,8a,9,10,11,12,12a,12b,13,14b-icosahydropicene-2-carboxylic acid

C₅₄H₇₈O₂₀

glycyrrizhin

(3β,20β)-20-carboxy-11-oxo-30-norolean-12-en-3-yl 2-O-β-D-glucopyranuronosyl-β-D-glucopyranosiduronic acid 6′ ,6′’-dimethyl ester

Downstream raw materials:

C₄₉H₇₁NO₁₄

Refernces