3-O-allyl-2,4,6-tri-O-acetyl-β-D-glucopyranosyl-(1->3)-[2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl-(1->6)]-1,2-O-isopropylidene-α-D-glucofuranose

Base Information

Chemical Name:3-O-allyl-2,4,6-tri-O-acetyl-β-D-glucopyranosyl-(1->3)-[2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl-(1->6)]-1,2-O-isopropylidene-α-D-glucofuranose
CAS No.:483361-30-4
Molecular Formula:C₅₈H₆₂O₂₃
Molecular Weight:1127.12
Hs Code.:

Synonyms:3-O-allyl-2,4,6-tri-O-acetyl-β-D-glucopyranosyl-(1->3)-[2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl-(1->6)]-1,2-O-isopropylidene-α-D-glucofuranose

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Chemical Property of 3-O-allyl-2,4,6-tri-O-acetyl-β-D-glucopyranosyl-(1->3)-[2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl-(1->6)]-1,2-O-isopropylidene-α-D-glucofuranose

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Technology Process of 3-O-allyl-2,4,6-tri-O-acetyl-β-D-glucopyranosyl-(1->3)-[2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl-(1->6)]-1,2-O-isopropylidene-α-D-glucofuranose

There total 10 articles about 3-O-allyl-2,4,6-tri-O-acetyl-β-D-glucopyranosyl-(1->3)-[2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl-(1->6)]-1,2-O-isopropylidene-α-D-glucofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 149707-75-5
2,3,4,6-tetra-O-benzoyl-D-glucopyranosyl trichloroacetimidate

: 483361-29-1
3-O-allyl-2,4,6-tri-O-acetyl-β-D-glucopyranosyl-(1->3)-1,2-O-isopropylidene-α-D-glucofuranose

: 483361-30-4
3-O-allyl-2,4,6-tri-O-acetyl-β-D-glucopyranosyl-(1->3)-[2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl-(1->6)]-1,2-O-isopropylidene-α-D-glucofuranose

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at 20 ℃; for 3h;
DOI:10.1016/S0968-0896(03)00118-4

Reference yield:

: 2592-58-7,3006-48-2,3006-49-3,13526-09-5,14679-57-3,22415-91-4,29884-70-6,41545-55-5,41545-56-6,41569-33-9,96996-90-6,121570-85-2,121570-86-3
1,2,3,4,6-penta-O-benzoyl-D-glucopyranoside

: 483361-30-4
3-O-allyl-2,4,6-tri-O-acetyl-β-D-glucopyranosyl-(1->3)-[2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl-(1->6)]-1,2-O-isopropylidene-α-D-glucofuranose

Guidance literature:: Multi-step reaction with 3 steps

1: ammonia / tetrahydrofuran; methanol / 12 h / 20 °C

2: 46 g / K₂CO₃ / CH₂Cl₂ / 24 h / 20 °C

3: 90 percent / trimethylsilyl trifluoromethanesulfonate / CH₂Cl₂ / 3 h / 20 °C

With trimethylsilyl trifluoromethanesulfonate; ammonia; potassium carbonate; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1016/S0968-0896(03)00118-4

Reference yield:

: 2280-44-6
D-Glucose

: 483361-30-4
3-O-allyl-2,4,6-tri-O-acetyl-β-D-glucopyranosyl-(1->3)-[2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl-(1->6)]-1,2-O-isopropylidene-α-D-glucofuranose

Guidance literature:: Multi-step reaction with 4 steps

1: trimethylsilyl trifluoromethanesulfonate / CH₂Cl₂ / 3 h / 20 °C

2: 15 g / acetic acid / H₂O / 24 h / 40 °C

3: 90 percent / trimethylsilyl trifluoromethanesulfonate / CH₂Cl₂ / 3 h / 20 °C

With trimethylsilyl trifluoromethanesulfonate; acetic acid; In dichloromethane; water;
DOI:10.1016/S0968-0896(03)00118-4