Technology Process of 4-phenylhexa-2,3-dien-1-ol
There total 1 articles about 4-phenylhexa-2,3-dien-1-ol which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
ethylmagnesium bromide;
With
tetrakis(acetonitrile)copper(I)tetrafluoroborate; tri-n-butyl phosphite;
In
diethyl ether; dichloromethane;
at -10 ℃;
for 0.5h;
Inert atmosphere;
4-(phenylethynyl)-1,3-dioxolan-2-one;
In
diethyl ether; dichloromethane;
at -10 ℃;
for 2h;
regioselective reaction;
Inert atmosphere;
DOI:10.1002/ejoc.200900226
- Guidance literature:
-
With
Iron(III) nitrate nonahydrate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; oxygen; sodium chloride;
In
1,2-dichloro-ethane;
at 20 ℃;
for 23h;
under 760.051 Torr;
DOI:10.1021/ol5021509
- Guidance literature:
-
Multi-step reaction with 2 steps
1: Iron(III) nitrate nonahydrate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium chloride; oxygen / 1,2-dichloro-ethane / 23 h / 20 °C / 760.05 Torr
2: 1,3-bis(mesityl)imidazolium chloride; potassium tert-butylate / tetrahydrofuran / 12 h / -10 - 25 °C / Schlenk technique; Inert atmosphere
With
Iron(III) nitrate nonahydrate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; potassium tert-butylate; oxygen; 1,3-bis(mesityl)imidazolium chloride; sodium chloride;
In
tetrahydrofuran; 1,2-dichloro-ethane;
DOI:10.1021/ol5021509
