(1R,2S,3R)-3-acetoxymethyl-2-(tert-butyldiphenylsiloxy)cyclobutanal

Base Information

Chemical Name:(1R,2S,3R)-3-acetoxymethyl-2-(tert-butyldiphenylsiloxy)cyclobutanal
CAS No.:140710-28-7
Molecular Formula:C₂₄H₃₀O₄Si
Molecular Weight:410.585
Hs Code.:

Synonyms:(1R,2S,3R)-3-acetoxymethyl-2-(tert-butyldiphenylsiloxy)cyclobutanal

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1R,2S,3R)-3-acetoxymethyl-2-(tert-butyldiphenylsiloxy)cyclobutanal

Chemical Property:

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Technology Process of (1R,2S,3R)-3-acetoxymethyl-2-(tert-butyldiphenylsiloxy)cyclobutanal

There total 7 articles about (1R,2S,3R)-3-acetoxymethyl-2-(tert-butyldiphenylsiloxy)cyclobutanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 140710-27-6
(1R,2R,3S)-1-acetoxymethyl-2-(tert-butyldiphenylsiloxy)-3-hydroxymethylcyclobutane

: 140710-28-7
(1R,2S,3R)-3-acetoxymethyl-2-(tert-butyldiphenylsiloxy)cyclobutanal

Guidance literature:: With pyridinium chlorochromate; In dichloromethane; for 3h;
DOI:10.1016/S0957-4166(00)80211-6

Reference yield:

: 133592-85-5
3-(2-Methyl-4-oxo-4H-[1,3]dioxin-2-yl)-propionic acid allyl ester

: 140710-28-7
(1R,2S,3R)-3-acetoxymethyl-2-(tert-butyldiphenylsiloxy)cyclobutanal

Guidance literature:: Multi-step reaction with 6 steps

1: 80 percent / ethyl acetate / 3 h / Irradiation

2: H₂O / acetonitrile / 8 h / 50 °C

3: imidazole / dimethylformamide / 48 h

4: 100 percent / LiBHEt₃ / tetrahydrofuran / 3 h / Ambient temperature

5: 72 h / 28 °C / lipase MY

6: 100 percent / PCC / CH₂Cl₂ / 3 h

With 1H-imidazole; water; lithium triethylborohydride; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1016/S0957-4166(00)80211-6

Reference yield:

: 133592-90-2,142758-71-2
(1R,7S,9S,13R)-1-Methyl-5,11,12-trioxa-tricyclo[5.4.2.0^9,13]tridecane-4,10-dione

: 140710-28-7
(1R,2S,3R)-3-acetoxymethyl-2-(tert-butyldiphenylsiloxy)cyclobutanal

Guidance literature:: Multi-step reaction with 5 steps

1: H₂O / acetonitrile / 8 h / 50 °C

2: imidazole / dimethylformamide / 48 h

3: 100 percent / LiBHEt₃ / tetrahydrofuran / 3 h / Ambient temperature

4: 72 h / 28 °C / lipase MY

5: 100 percent / PCC / CH₂Cl₂ / 3 h

With 1H-imidazole; water; lithium triethylborohydride; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1016/S0957-4166(00)80211-6