1-{1-(1,1-dimethylethyl)-3-[4-(oct-7-en-1-yl)phenyl]-3-phenylpropa-1,2-dienyl}-4-(oct-7-en-1-yl)benzene

Base Information

Chemical Name:1-{1-(1,1-dimethylethyl)-3-[4-(oct-7-en-1-yl)phenyl]-3-phenylpropa-1,2-dienyl}-4-(oct-7-en-1-yl)benzene
CAS No.:861721-85-9
Molecular Formula:C₄₁H₅₂
Molecular Weight:544.864
Hs Code.:

Synonyms:1-{1-(1,1-dimethylethyl)-3-[4-(oct-7-en-1-yl)phenyl]-3-phenylpropa-1,2-dienyl}-4-(oct-7-en-1-yl)benzene

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Chemical Property of 1-{1-(1,1-dimethylethyl)-3-[4-(oct-7-en-1-yl)phenyl]-3-phenylpropa-1,2-dienyl}-4-(oct-7-en-1-yl)benzene

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Technology Process of 1-{1-(1,1-dimethylethyl)-3-[4-(oct-7-en-1-yl)phenyl]-3-phenylpropa-1,2-dienyl}-4-(oct-7-en-1-yl)benzene

There total 7 articles about 1-{1-(1,1-dimethylethyl)-3-[4-(oct-7-en-1-yl)phenyl]-3-phenylpropa-1,2-dienyl}-4-(oct-7-en-1-yl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 861721-84-8
1-bromo-4-[3-(4-bromophenyl)-1-(1,1-dimethylethyl)-3-phenylpropa-1,2-dienyl]benzene

: 2695-48-9
8-Bromo-1-octene

: 861721-85-9
1-{1-(1,1-dimethylethyl)-3-[4-(oct-7-en-1-yl)phenyl]-3-phenylpropa-1,2-dienyl}-4-(oct-7-en-1-yl)benzene

Guidance literature:: 8-Bromo-1-octene; With magnesium; In diethyl ether; for 1.5h; Heating;

1-bromo-4-[3-(4-bromophenyl)-1-(1,1-dimethylethyl)-3-phenylpropa-1,2-dienyl]benzene; 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); In diethyl ether; for 13h; Heating;
DOI:10.1002/ejoc.200500096

Reference yield:

: 861721-94-0
1,3-bis(4-bromophenyl)prop-2-yn-1-ol

: 861721-85-9
1-{1-(1,1-dimethylethyl)-3-[4-(oct-7-en-1-yl)phenyl]-3-phenylpropa-1,2-dienyl}-4-(oct-7-en-1-yl)benzene

Guidance literature:: Multi-step reaction with 5 steps

1.1: 64 percent / IBX / dimethylsulfoxide / 3 h / 20 °C

2.1: 96 percent / tetrahydrofuran; cyclohexane; diethyl ether / 2 h / -50 °C

3.1: 60 percent / triethylamine; 4-(N,N-dimethylamino)pyridine / CH₂Cl₂ / 12 h / 20 °C

4.1: 68 percent / LiBr; CuI / tetrahydrofuran; diethyl ether / 0.67 h / 0 °C

5.1: magnesium / diethyl ether / 1.5 h / Heating

5.2: 87 percent / 1,3-bis(diphenylphosphanyl)propanickel(II) chloride / diethyl ether / 13 h / Heating

With dmap; copper(l) iodide; magnesium; triethylamine; lithium bromide; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; diethyl ether; dichloromethane; cyclohexane; dimethyl sulfoxide; 5.2: Kumada cross coupling;
DOI:10.1002/ejoc.200500096

Reference yield:

: 861721-83-7
1,3-bis(4-bromophenyl)-1-phenylprop-2-yn-1-ol

: 861721-85-9
1-{1-(1,1-dimethylethyl)-3-[4-(oct-7-en-1-yl)phenyl]-3-phenylpropa-1,2-dienyl}-4-(oct-7-en-1-yl)benzene

Guidance literature:: Multi-step reaction with 3 steps

1.1: 60 percent / triethylamine; 4-(N,N-dimethylamino)pyridine / CH₂Cl₂ / 12 h / 20 °C

2.1: 68 percent / LiBr; CuI / tetrahydrofuran; diethyl ether / 0.67 h / 0 °C

3.1: magnesium / diethyl ether / 1.5 h / Heating

3.2: 87 percent / 1,3-bis(diphenylphosphanyl)propanickel(II) chloride / diethyl ether / 13 h / Heating

With dmap; copper(l) iodide; magnesium; triethylamine; lithium bromide; In tetrahydrofuran; diethyl ether; dichloromethane; 3.2: Kumada cross coupling;
DOI:10.1002/ejoc.200500096