Technology Process of (1R,3R,4S,4aS,8aS,9aR,10aS)-4-Benzyloxy-3-ethylsulfanyl-1-isobutyl-8a,10a-dimethoxy-decahydro-2,9,10-trioxa-anthracene
There total 5 articles about (1R,3R,4S,4aS,8aS,9aR,10aS)-4-Benzyloxy-3-ethylsulfanyl-1-isobutyl-8a,10a-dimethoxy-decahydro-2,9,10-trioxa-anthracene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
hydrogen; ethylenediamine;
palladium on activated charcoal;
In
methanol; water;
at 20 ℃;
for 12h;
under 37.503 Torr;
DOI:10.1021/jm020487h
- Guidance literature:
-
Multi-step reaction with 4 steps
1: KOH / dimethylsulfoxide
2: Et3N; Py*SO3 / CH2Cl2; dimethylsulfoxide / 0.5 h / 0 °C
3: KN[Si(CH3)3]2 / toluene / 3.5 h / -10 - 20 °C
4: 80 percent / H2; ethylenediamine / Pd/C / methanol; H2O / 12 h / 20 °C / 37.5 Torr
With
potassium hydroxide; hydrogen; sulfur trioxide pyridine complex; potassium hexamethylsilazane; ethylenediamine; triethylamine;
palladium on activated charcoal;
In
methanol; dichloromethane; water; dimethyl sulfoxide; toluene;
1: Williamson reaction / 3: Wittig olefination;
DOI:10.1021/jm020487h
- Guidance literature:
-
Multi-step reaction with 4 steps
1: KOH / dimethylsulfoxide
2: Et3N; Py*SO3 / CH2Cl2; dimethylsulfoxide / 0.5 h / 0 °C
3: KN[Si(CH3)3]2 / toluene / 3.5 h / -10 - 20 °C
4: 80 percent / H2; ethylenediamine / Pd/C / methanol; H2O / 12 h / 20 °C / 37.5 Torr
With
potassium hydroxide; hydrogen; sulfur trioxide pyridine complex; potassium hexamethylsilazane; ethylenediamine; triethylamine;
palladium on activated charcoal;
In
methanol; dichloromethane; water; dimethyl sulfoxide; toluene;
1: Williamson reaction / 3: Wittig olefination;
DOI:10.1021/jm020487h
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