1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane

Base Information

Chemical Name:1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane
CAS No.:97739-46-3
Molecular Formula:C16H21 O3 P
Molecular Weight:292.315
Hs Code.:
DSSTox Substance ID:DTXSID50699640
Mol file:97739-46-3.mol

Synonyms:1,3,5,7-tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane;TT-PPA cpd

Suppliers and Price of 1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantane, 99% MeCgPPh
500mg
$ 85.00

Strem Chemicals
1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantane, 99% MeCgPPh
2g
$ 254.00

Sigma-Aldrich
1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane 97%
2g
$ 278.00

Sigma-Aldrich
1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane 97%
500mg
$ 84.70

ChemSupplyAustralia
1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane, 98%
500 mg
$ 70.40

Chemenu
1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane 95%+
500mg
$ 230.00

Arctom
1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane 98%
1g
$ 138.00

Arctom
1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane 98%
100mg
$ 48.00

Arctom
1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane 98%
250mg
$ 68.00

Arctom
1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane 98%
5g
$ 406.00

Total 39 raw suppliers

Chemical Property of 1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane

Chemical Property:

Melting Point:106-111 °C
Boiling Point:363.4±42.0 °C(Predicted)
PSA：41.28000
LogP:3.52940
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
Sensitive.:air sensitive, moisture sensitiv
XLogP3:2.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:292.12283153
Heavy Atom Count:20
Complexity:407

Purity/Quality:

98% ^*data from raw suppliers

1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantane, 99% MeCgPPh ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 36/37/38
Safety Statements: 26-37

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC12CC3(OC(O1)(CC(O2)(P3C4=CC=CC=C4)C)C)C
Uses A bulky, robust, and electron-poor ligand that gives efficient rhodium hydroformylation and palladium cross-coupling catalysts. 1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane can be used:As a ligand to synthesize complexes for hydroformylation catalysis.To catalyze the synthesis of dibenzo[b,f][1,4]oxazepin-11(10H)-ones and 3-methyl-3,4-dihydrocoumarins by intramolecular cyclocarbonylation.

Technology Process of 1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane

There total 3 articles about 1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 108-86-1,52753-63-6
bromobenzene

: 26088-25-5
1,3,5,7-tetramethyl-2,4,8-trioxa-6-phosphaadamantane

: 97739-46-3
1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane

Guidance literature:: With triethylamine; trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II); for 40h; Heating;
DOI:10.1021/ol0341647