7-(2-((E)-2-((1RS,2SR,3RS)-2,3-diphenylcyclopropyl)vinyl)phenyl)cyclohepta-1,3,5-triene

Base Information

Chemical Name:7-(2-((E)-2-((1RS,2SR,3RS)-2,3-diphenylcyclopropyl)vinyl)phenyl)cyclohepta-1,3,5-triene
CAS No.:1528732-66-2
Molecular Formula:C₃₀H₂₆
Molecular Weight:386.536
Hs Code.:

Synonyms:7-(2-((E)-2-((1RS,2SR,3RS)-2,3-diphenylcyclopropyl)vinyl)phenyl)cyclohepta-1,3,5-triene

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Chemical Property of 7-(2-((E)-2-((1RS,2SR,3RS)-2,3-diphenylcyclopropyl)vinyl)phenyl)cyclohepta-1,3,5-triene

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Technology Process of 7-(2-((E)-2-((1RS,2SR,3RS)-2,3-diphenylcyclopropyl)vinyl)phenyl)cyclohepta-1,3,5-triene

There total 3 articles about 7-(2-((E)-2-((1RS,2SR,3RS)-2,3-diphenylcyclopropyl)vinyl)phenyl)cyclohepta-1,3,5-triene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 1528732-51-5
((1R,2S,3s)-3-((E)-2-bromostyryl)cyclopropane-1,2-diyl)dibenzene

: 1528732-66-2
7-(2-((E)-2-((1RS,2SR,3RS)-2,3-diphenylcyclopropyl)vinyl)phenyl)cyclohepta-1,3,5-triene

Guidance literature:: ((1R,2S,3s)-3-((E)-2-bromostyryl)cyclopropane-1,2-diyl)dibenzene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h; Inert atmosphere;

tropylium derivative; In tetrahydrofuran; hexane; at 23 ℃; for 12h; Inert atmosphere;
DOI:10.1021/ja411626v

Reference yield:

: 64200-26-6
trans-2,trans-3-diphenylcyclopropanecarboxaldehyde

: 1528732-66-2
7-(2-((E)-2-((1RS,2SR,3RS)-2,3-diphenylcyclopropyl)vinyl)phenyl)cyclohepta-1,3,5-triene

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hydride / tetrahydrofuran / 1 h / 0 - 23 °C / Inert atmosphere

1.2: 12 h / 0 - 23 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere

2.2: 12 h / 23 °C / Inert atmosphere

With n-butyllithium; sodium hydride; In tetrahydrofuran; hexane;
DOI:10.1021/ja411626v

Reference yield:

: 63909-55-7
diethyl 2-bromobenzylphosphonate

: 1528732-66-2
7-(2-((E)-2-((1RS,2SR,3RS)-2,3-diphenylcyclopropyl)vinyl)phenyl)cyclohepta-1,3,5-triene

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hydride / tetrahydrofuran / 1 h / 0 - 23 °C / Inert atmosphere

1.2: 12 h / 0 - 23 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere

2.2: 12 h / 23 °C / Inert atmosphere

With n-butyllithium; sodium hydride; In tetrahydrofuran; hexane;
DOI:10.1021/ja411626v