[Pd(dppe)(Me)(PMes₂H)]OTf

Base Information

Chemical Name:[Pd(dppe)(Me)(PMes₂H)]OTf
CAS No.:250717-55-6
Molecular Formula:CF₃O₃S*C₄₅H₅₀P₃Pd
Molecular Weight:939.304
Hs Code.:

Synonyms:[Pd(dppe)(Me)(PMes₂H)]OTf

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Chemical Property of [Pd(dppe)(Me)(PMes₂H)]OTf

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Technology Process of [Pd(dppe)(Me)(PMes₂H)]OTf

There total 2 articles about [Pd(dppe)(Me)(PMes₂H)]OTf which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 64406-71-9
[1,1'-bis(diphenylphosphino)ethane(Pd(CH3)Cl)]

: 1732-66-7
dimesityl phosphine

: 2923-28-6
silver trifluoromethanesulfonate

: 250717-55-6
[Pd(dppe)(Me)(PMes₂H)]OTf

Guidance literature:: In tetrahydrofuran; acetonitrile; byproducts: AgCl; PHMes2 and AgOTf were added to a stirred suspn. of complex in THF and CH3CN, protected from light, stirred for 60 min at 20°C under N2; filtered, reduced in vol., petroleum ether was added, cooled to -25°C; elem. anal.;
DOI:10.1021/om000164o

Reference yield:

: 287945-30-6
PdP(C₆H₅)2C₂H₄P(C₆H₅)2PH(C₆H₂(CH₃)3)2Cl⁽¹⁺⁾*O₃SCF₃^(1-)=PdP₂(C₆H₅)4C₂H₄PH(C₆H₂(CH₃)3)2Cl(SO₃CF₃)

: 250717-55-6
[Pd(dppe)(Me)(PMes₂H)]OTf

Guidance literature:: Multi-step reaction with 2 steps

1: acetone

2: acetonitrile; tetrahydrofuran

In tetrahydrofuran; acetone; acetonitrile;
DOI:10.1021/om000164o

Reference yield: 85.0%

: 250717-55-6
[Pd(dppe)(Me)(PMes₂H)]OTf

: 287945-23-7
PdP(C₆H₅)2C₂H₄P(C₆H₅)2PH(C₆H₂(CH₃)3)(CH₂C₆H₂(CH₃)2)⁽¹⁺⁾*CF₃SO₃^(1-)

Guidance literature:: With CF₃SO₃H; In acetone; HOTf in acetone was added to a soln. of complex in acetone, heated for 3 d at 60°C (N2); filtered, Et2O was added, cooled to -25°C, slow evapd. from THF-toluene; elem. anal.;
DOI:10.1021/om000164o