4-benzyl-2-{2-[2-(tert-butyl-dimethyl-silanyloxy)-phenyl]-1-phenyl-ethylidene}-morpholine

Base Information

Chemical Name:4-benzyl-2-{2-[2-(tert-butyl-dimethyl-silanyloxy)-phenyl]-1-phenyl-ethylidene}-morpholine
CAS No.:935762-23-5
Molecular Formula:C₃₁H₃₉NO₂Si
Molecular Weight:485.742
Hs Code.:

Synonyms:4-benzyl-2-{2-[2-(tert-butyl-dimethyl-silanyloxy)-phenyl]-1-phenyl-ethylidene}-morpholine

Suppliers and Price of 4-benzyl-2-{2-[2-(tert-butyl-dimethyl-silanyloxy)-phenyl]-1-phenyl-ethylidene}-morpholine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemicals and raw materials
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Total 2 raw suppliers

Chemical Property of 4-benzyl-2-{2-[2-(tert-butyl-dimethyl-silanyloxy)-phenyl]-1-phenyl-ethylidene}-morpholine

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of 4-benzyl-2-{2-[2-(tert-butyl-dimethyl-silanyloxy)-phenyl]-1-phenyl-ethylidene}-morpholine

There total 3 articles about 4-benzyl-2-{2-[2-(tert-butyl-dimethyl-silanyloxy)-phenyl]-1-phenyl-ethylidene}-morpholine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 860013-73-6
E-trifluoro-methanesulfonic acid (4-benzyl-morpholin-2-ylidene)-phenyl-methyl ester

: 935762-23-5
4-benzyl-2-{2-[2-(tert-butyl-dimethyl-silanyloxy)-phenyl]-1-phenyl-ethylidene}-morpholine

Guidance literature:: tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 95 ℃; for 1h;
DOI:10.1016/j.tetlet.2007.02.013

Reference yield:

: 521969-46-0
(4-benzyl-morpholin-2-yl)-phenylmethanone

: 935762-23-5
4-benzyl-2-{2-[2-(tert-butyl-dimethyl-silanyloxy)-phenyl]-1-phenyl-ethylidene}-morpholine

Guidance literature:: Multi-step reaction with 2 steps

1.1: tBuOK; 18-crown-6; H₂O / tetrahydrofuran / 1 h / 0 - 20 °C

1.2: tetrahydrofuran / 20 °C

2.1: 76 percent / Pd(PPh₃)4 / tetrahydrofuran / 1 h / 95 °C

With 18-crown-6 ether; potassium tert-butylate; water; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran;
DOI:10.1016/j.tetlet.2007.02.013