(R)-1-cyclohexyl-2-<(tert-butyldimethylsilyl)oxy>ethyl (E,E,E)-12-methyltrideca-2,8,10-trienoate

Base Information

Chemical Name:(R)-1-cyclohexyl-2-<(tert-butyldimethylsilyl)oxy>ethyl (E,E,E)-12-methyltrideca-2,8,10-trienoate
CAS No.:92126-41-5
Molecular Formula:C₂₈H₅₀O₃Si
Molecular Weight:462.789
Hs Code.:

Synonyms:(R)-1-cyclohexyl-2-<(tert-butyldimethylsilyl)oxy>ethyl (E,E,E)-12-methyltrideca-2,8,10-trienoate

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Chemical Property of (R)-1-cyclohexyl-2-<(tert-butyldimethylsilyl)oxy>ethyl (E,E,E)-12-methyltrideca-2,8,10-trienoate

Chemical Property:

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Technology Process of (R)-1-cyclohexyl-2-<(tert-butyldimethylsilyl)oxy>ethyl (E,E,E)-12-methyltrideca-2,8,10-trienoate

There total 6 articles about (R)-1-cyclohexyl-2-<(tert-butyldimethylsilyl)oxy>ethyl (E,E,E)-12-methyltrideca-2,8,10-trienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1-cyclohexyl-2-<(tert-butyldimethylsilyl)oxy>ethanol

: 92126-41-5
(R)-1-cyclohexyl-2-<(tert-butyldimethylsilyl)oxy>ethyl (E,E,E)-12-methyltrideca-2,8,10-trienoate

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine / CH₂Cl₂ / 1.5 h / 0 - 23 °C

2: 95 percent / toluene / 5 h / Heating

3: 1. LDA / 1. THF, 15 min, -40 deg C 2. THF, a.) 10 min, -40 deg C b.) 6 h, room temp.

With pyridine; lithium diisopropyl amide; In dichloromethane; toluene;
DOI:10.1021/jo00198a018

Reference yield:

: Bromo-acetic acid 2-(tert-butyl-dimethyl-silanyloxy)-1-cyclohexyl-ethyl ester

: 92126-41-5
(R)-1-cyclohexyl-2-<(tert-butyldimethylsilyl)oxy>ethyl (E,E,E)-12-methyltrideca-2,8,10-trienoate

Guidance literature:: Multi-step reaction with 2 steps

1: 95 percent / toluene / 5 h / Heating

2: 1. LDA / 1. THF, 15 min, -40 deg C 2. THF, a.) 10 min, -40 deg C b.) 6 h, room temp.

With lithium diisopropyl amide; In toluene;
DOI:10.1021/jo00198a018

Reference yield:

: 59411-58-4,61414-09-3,87858-06-8,125874-67-1
(R)-(-)-1-cyclohexyl-1,2-ethylene glycol

: 92126-41-5
(R)-1-cyclohexyl-2-<(tert-butyldimethylsilyl)oxy>ethyl (E,E,E)-12-methyltrideca-2,8,10-trienoate

Guidance literature:: Multi-step reaction with 4 steps

1: (dimethylamino)pyridine, triethylamine / CH₂Cl₂ / 15 h / 23 °C

2: pyridine / CH₂Cl₂ / 1.5 h / 0 - 23 °C

3: 95 percent / toluene / 5 h / Heating

4: 1. LDA / 1. THF, 15 min, -40 deg C 2. THF, a.) 10 min, -40 deg C b.) 6 h, room temp.

With pyridine; dmap; triethylamine; lithium diisopropyl amide; In dichloromethane; toluene;
DOI:10.1021/jo00198a018