(η5-C5H5)2Zr(H)(CH2Cy)

Base Information

• Chemical Name: (η5-C5H5)2Zr(H)(CH2Cy)
• CAS No.: 69058-71-5
• Molecular Formula: C₁₇H₂₄Zr
• Molecular Weight: 319.602
• Mol file: 69058-71-5.mol

Synonyms:(η5-C5H5)2Zr(H)(CH2Cy)

Chemical Property of (η5-C5H5)2Zr(H)(CH2Cy)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (η5-C5H5)2Zr(H)(CH2Cy)

There total 1 articles about (η5-C5H5)2Zr(H)(CH2Cy) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

(C5H5)2ZrClCH2CH(CH2)5 (54634-15-0) + lithium tri-t-butoxyaluminum hydride → (η5-C5H5)2Zr(H)(CH2Cy) (69058-71-5)

Guidance literature:

In 1,2-dimethoxyethane; hydride was added dropwise to soln. of Zr complex at -30°C (Ar) over 30 min; react. time 12 h; filtration at -50°C; washing with DME, hexane, drying in vac.;

DOI:10.1021/ja00371a012

Reference yield: 90.0%

(η5-C5H5)2Zr(H)(CH2Cy) (69058-71-5) → zirconocene dichloride (1291-32-3)

Guidance literature:

With HCl; In octane; toluene; byproducts: H2; treating with HCl at -80°C (Ar); after 45 min slow warming to room temp.;

DOI:10.1021/ja00371a012

Reference yield: 80.0%

(η5-C5H5)2Zr(H)(CH2Cy) (69058-71-5) → (η5-cyclopentadienyl)2Zr(Ph)(OPr-i)

Guidance literature:

With acetone; diphenyl(methyl)phosphine; benzene; In benzene; under Ar phosphine added to Zr-compd./C6H6, stirred, acetone added, stirred for 12 h; solvent removed, MeI added, (PMe2Ph2)I removed;

DOI:10.1021/ja00400a033

upstream raw materials:

(C₅H₅)2ZrClCH₂CH(CH₂)5

Downstream raw materials:

zirconocene dichloride

(C₅H₅)2Zr(CO)(P(CH₃)(C₆H₅)2)

zirconocene dicarbonyl

(C₅H₅)2ZrClCH₂CH(CH₂)5