zirconocene dicarbonyl

Base Information

• Chemical Name: zirconocene dicarbonyl
• CAS No.: 59487-85-3
• Molecular Formula: C₁₂H₁₀O₂Zr
• Molecular Weight: 277.434
• Mol file: 59487-85-3.mol

Synonyms:zirconocene dicarbonyl

Chemical Property of zirconocene dicarbonyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of zirconocene dicarbonyl

There total 1 articles about zirconocene dicarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(η5-C5H5)2Zr(H)(CH2Cy) (69058-71-5) → (C5H5)2Zr(CO)(P(CH3)(C6H5)2) (71844-75-2) + zirconocene dicarbonyl (59487-85-3)

Guidance literature:

With carbon monoxide; diphenyl(methyl)phosphine; In benzene; under Ar phosphine added to Zr-compd./C6H6, stirred, filled with CO, stirred for 6 h; products not sepd., detected by NMR, IR;

DOI:10.1021/ja00400a033

Reference yield: 98.0%

zirconocene dicarbonyl (59487-85-3) + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) → (C5H5)2Zr(CO)(CNC8H9) (104738-36-5)

Guidance literature:

In pentane; byproducts: CO; Ar-atmosphere; stirring (room temp., 20 h); filtration, concn., crystn. (-20°C), decantation; elem. anal.;

Reference yield: 80.0%

zirconocene dicarbonyl (59487-85-3) + benzophenone azine (983-79-9) → Cp2Zr(N=CPh2)2 (11106-18-6)

Guidance literature:

In benzene; other Radiation; benzene soln. of the zirconocene dicarbonyl and benzophenone azine irradiated for 2 h with stirring; solvent removed in vacuo; remaining residue stirred with pentane and solid product collected by filtration; elem. anal.;

DOI:10.1021/ja00216a011

upstream raw materials:

(η5-C5H5)2Zr(H)(CH2Cy)

Downstream raw materials:

zirconium(IV) oxide

Cp₂Zr(N=CPh₂)2

(C₅H₅)2Zr(CO)(P(CH₃)2C₆H₅)

1,1-bis(cyclopentadienyl)zircona-2,3,4,5-tetraphenylcyclopentadiene