[(((CH₃)2CH)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)Ti(CH₂C(CH₃)3)2]

Base Information

• Chemical Name: [(((CH₃)2CH)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)Ti(CH₂C(CH₃)3)2]
• CAS No.: 543740-55-2
• Molecular Formula: C₃₉H₆₃N₂Ti
• Molecular Weight: 607.823
• Mol file: 543740-55-2.mol

Synonyms:[(((CH₃)2CH)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)Ti(CH₂C(CH₃)3)2]

Chemical Property of [(((CH₃)2CH)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)Ti(CH₂C(CH₃)3)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(((CH₃)2CH)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)Ti(CH₂C(CH₃)3)2]

There total 1 articles about [(((CH₃)2CH)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)Ti(CH₂C(CH₃)3)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

[([2,6-iPr2C6H3]NC(Me)CHC(Me)N[2,6-iPr2C6H3])TiCl2·THF] (543740-53-0) + neopentyl lithium (7412-67-1) → [(((CH3)2CH)2C6H3NC(CH3)CHC(CH3)NC6H3(CH(CH3)2)2)Ti(CH2C(CH3)3)2] (543740-55-2)

Guidance literature:

In diethyl ether; byproducts: THF, LiCl; Ti complex was reacted with Li compd. (2 equiv.) in Et2O at -35°C;

DOI:10.1021/ja034786n

Reference yield: 92.0%

[(((CH3)2CH)2C6H3NC(CH3)CHC(CH3)NC6H3(CH(CH3)2)2)Ti(CH2C(CH3)3)2] (543740-55-2) + decamethylferrocenium tetrakis(pentafluorophenyl)borate (135348-60-6) → (C6H3(CH(CH3)2)2NCCH3CHCCH3NC6H3(CH(CH3)2)2)Ti(CH2C(CH3)3)2(1+)*B(C6F5)4(1-)=((C6H3(C3H7)2NCCH3)2CH)Ti(CH2C4H9)2B(C6F5)4 (851530-31-9)

Guidance literature:

In diethyl ether; N2 atm.; to a cold soln. of complex in diethyl ether at -35°C wasadded cold soln. of ferrocenium-compound in diethyl ether, the soln. wa s allowed to stir for 3 min; filtered, dried under reduced pressure, washed with pentane, extd. with diethyl ether, filtered, concd., a few drops of ((CH3)3Si)2O were added,cooled to -35°C ; elem. anal.;

DOI:10.1021/om049400b

Reference yield: 61.0%

[(((CH3)2CH)2C6H3NC(CH3)CHC(CH3)NC6H3(CH(CH3)2)2)Ti(CH2C(CH3)3)2] (543740-55-2) + iodine (7553-56-2,12190-71-5,8031-47-8) → (C6H3(CH(CH3)2)2NCCH3CHCCH3NC6H3(CH(CH3)2)2)Ti(CHC(CH3)3)I

Guidance literature:

In toluene; N2 atm.; to a soln. of complex in toluene at -35°C was added a cold toluene soln. of iodine, the mixt. was allowed to stir 15 min; the mixt. was pumped dry, dissolved in pentane, filtered, concd., cooledto -35°C; elem. anal.;

DOI:10.1021/om049400b

upstream raw materials:

[([2,6-iPr₂C₆H₃]NC(Me)CHC(Me)N[2,6-iPr₂C₆H₃])TiCl₂·THF]

neopentyl lithium

Downstream raw materials:

(C₆H₃(CH(CH₃)2)2NCCH₃CHCCH₃NC₆H₃(CH(CH₃)2)2)Ti(CH₂C(CH₃)3)2⁽¹⁺⁾*B(C₆F₅)4^(1-)=((C₆H₃(C₃H₇)2NCCH₃)2CH)Ti(CH₂C₄H₉)2B(C₆F₅)4

(C₆H₃(CH(CH₃)2)2NCCH₃CHCCH₃NC₆H₃(CH(CH₃)2)2)Ti(CH₂C(CH₃)3)2F