Technology Process of Fe3(CO)11(P(C6H5)3)
There total 3 articles about Fe3(CO)11(P(C6H5)3) which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
PPh3;
In
dichloromethane;
byproducts: CH3CN; addn. of PPh3 to soln. of {Fe3(CO)11(NCCH3)} in CH2Cl2 at -50°C, after consumption of starting nitrile complex (TLC), allowing to warm to -20°C; removing volatiles under vacuum at -20°C, recrystn. from dry, degassed hexane under N2 at -27°C, elem. anal.;
DOI:10.1016/0022-328X(88)89099-5
- Guidance literature:
-
With
trimethylamine-N-oxide;
In
ethanol; chloroform;
byproducts: CO2; kinetics and mechanism of the reaction investigated by UV/VIS and IR spectra;
Kinetics;
DOI:10.1021/ja00216a013
- Guidance literature:
-
With
P(C6H5)3;
In
tetrahydrofuran;
reaction for 20 min at room temperature with a catalytic amount of THF sodium diphenylketyl; preparative TLC (silica; hexane/CH2Cl2 9:1); elem. anal.;
DOI:10.1016/0022-328X(86)80526-5
