3-benzyl-2-phenyl-3-azabicyclo[3.2.0]hepta-1,4-diene

Base Information

Chemical Name:3-benzyl-2-phenyl-3-azabicyclo[3.2.0]hepta-1,4-diene
CAS No.:1646540-58-0
Molecular Formula:C₁₉H₁₇N
Molecular Weight:259.351
Hs Code.:

Synonyms:3-benzyl-2-phenyl-3-azabicyclo[3.2.0]hepta-1,4-diene

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Chemical Property of 3-benzyl-2-phenyl-3-azabicyclo[3.2.0]hepta-1,4-diene

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Technology Process of 3-benzyl-2-phenyl-3-azabicyclo[3.2.0]hepta-1,4-diene

There total 6 articles about 3-benzyl-2-phenyl-3-azabicyclo[3.2.0]hepta-1,4-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: (E)-1-phenyl-N-((1-(phenylethynyl)cyclopropyl)methylene)methanamine

: 1646540-58-0
3-benzyl-2-phenyl-3-azabicyclo[3.2.0]hepta-1,4-diene

Guidance literature:: With dodecacarbonyl-triangulo-triruthenium; In toluene; at 100 ℃; for 10h; chemoselective reaction; Inert atmosphere; Schlenk technique;
DOI:10.1002/anie.201405215

Reference yield: 61.0%

: 201230-82-2
carbon monoxide

: (E)-1-phenyl-N-((1-(phenylethynyl)cyclopropyl)methylene)methanamine

: 1646540-58-0
3-benzyl-2-phenyl-3-azabicyclo[3.2.0]hepta-1,4-diene

: 1646540-83-1
2-benzyl-3-phenyl-5,6-dihydrocyclopenta[c]pyrrol-4(2H)-one

Guidance literature:: With di(rhodium)tetracarbonyl dichloride; In para-xylene; at 100 ℃; for 10h; under 760.051 Torr; chemoselective reaction; Schlenk technique;
DOI:10.1002/anie.201405215

Reference yield:

: 591-50-4
iodobenzene

: 1646540-58-0
3-benzyl-2-phenyl-3-azabicyclo[3.2.0]hepta-1,4-diene

Guidance literature:: Multi-step reaction with 4 steps

1.1: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine / 20 °C

2.1: n-butyllithium / tetrahydrofuran; hexane / 2 h / 0 - 20 °C

2.2: 1 h / 0 °C

3.1: magnesium sulfate / dichloromethane / 50 °C / Sealed tube; Inert atmosphere

4.1: di(rhodium)tetracarbonyl dichloride / para-xylene / 10 h / 100 °C / 760.05 Torr / Schlenk technique

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; n-butyllithium; di(rhodium)tetracarbonyl dichloride; magnesium sulfate; triethylamine; In tetrahydrofuran; hexane; dichloromethane; para-xylene;
DOI:10.1002/anie.201405215