C₃₉H₅₄O₁₂

Base Information

• Chemical Name: C₃₉H₅₄O₁₂
• CAS No.: 1392098-17-7
• Molecular Formula: C₃₉H₅₄O₁₂
• Molecular Weight: 714.851
• Mol file: 1392098-17-7.mol

Synonyms:C₃₉H₅₄O₁₂

Chemical Property of C₃₉H₅₄O₁₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₉H₅₄O₁₂

There total 20 articles about C₃₉H₅₄O₁₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

C47H70O12Si (1392098-13-3) → C39H54O12 (1392098-17-7)

Guidance literature:

With tri-n-butylamine hydrofluoride; In tetrahydrofuran; at 20 ℃; for 48h;

DOI:10.3762/bjoc.8.82

Reference yield:

2-iodo-3,5-bis(phenylmethoxy)benzenemethanol (934243-80-8) → C39H54O12 (1392098-17-7)

Guidance literature:

Multi-step reaction with 11 steps

1.1: pyridine / dichloromethane / 3 h / 20 °C

2.1: tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; sodium t-butanolate / toluene / Inert atmosphere

2.2: 6 h / 50 °C / Inert atmosphere

3.1: diisobutylaluminium hydride / hexane; dichloromethane / 1.08 h / -78 - 20 °C / Inert atmosphere

4.1: sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 2 h / 0 - 20 °C / Inert atmosphere

5.1: palladium 10% on activated carbon; hydrogen; sodium hydrogencarbonate / tetrahydrofuran / 1.5 h / 20 °C

6.1: dmap; N-ethyl-N,N-diisopropylamine / dichloromethane / 96 h / 20 °C

7.1: tri-n-butylamine hydrofluoride / tetrahydrofuran / 48 h / 20 °C

8.1: tetra-n-butylammoniumfluoride trihydrate / tetrahydrofuran / 72 h / 20 °C

9.1: N,N-dimethyl-formamide / 1.5 h / -40 °C

9.2: 0.5 h / -40 - 20 °C

10.1: dmap / toluene / 3 h / 20 °C

11.1: tri-n-butylamine hydrofluoride / tetrahydrofuran / 48 h / 20 °C

With pyridine; dmap; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; palladium 10% on activated carbon; hydrogen; tri-n-butylamine hydrofluoride; diisobutylaluminium hydride; sodium hydrogencarbonate; tetra-n-butylammoniumfluoride trihydrate; N-ethyl-N,N-diisopropylamine; 3-chloro-benzenecarboperoxoic acid; sodium t-butanolate; In tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide; toluene;

DOI:10.3762/bjoc.8.82

Reference yield:

2-iodo-3,5-bis(phenylmethoxy)-(2',2'-dimethylpropanoyloxymethyl)benzene (934243-67-1) → C39H54O12 (1392098-17-7)

Guidance literature:

Multi-step reaction with 10 steps

1.1: tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; sodium t-butanolate / toluene / Inert atmosphere

1.2: 6 h / 50 °C / Inert atmosphere

2.1: diisobutylaluminium hydride / hexane; dichloromethane / 1.08 h / -78 - 20 °C / Inert atmosphere

3.1: sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 2 h / 0 - 20 °C / Inert atmosphere

4.1: palladium 10% on activated carbon; hydrogen; sodium hydrogencarbonate / tetrahydrofuran / 1.5 h / 20 °C

5.1: dmap; N-ethyl-N,N-diisopropylamine / dichloromethane / 96 h / 20 °C

6.1: tri-n-butylamine hydrofluoride / tetrahydrofuran / 48 h / 20 °C

7.1: tetra-n-butylammoniumfluoride trihydrate / tetrahydrofuran / 72 h / 20 °C

8.1: N,N-dimethyl-formamide / 1.5 h / -40 °C

8.2: 0.5 h / -40 - 20 °C

9.1: dmap / toluene / 3 h / 20 °C

10.1: tri-n-butylamine hydrofluoride / tetrahydrofuran / 48 h / 20 °C

With dmap; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; palladium 10% on activated carbon; hydrogen; tri-n-butylamine hydrofluoride; diisobutylaluminium hydride; sodium hydrogencarbonate; tetra-n-butylammoniumfluoride trihydrate; N-ethyl-N,N-diisopropylamine; 3-chloro-benzenecarboperoxoic acid; sodium t-butanolate; In tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide; toluene;

DOI:10.3762/bjoc.8.82

upstream raw materials:

2-iodo-3,5-bis(phenylmethoxy)benzenemethanol

2-iodo-3,5-bis(phenylmethoxy)-(2',2'-dimethylpropanoyloxymethyl)benzene

C₄₉H₇₂O₈Si₂

2-[1,5-anhydro-2-deoxy-4,6-O-(di-tert-butylsilylidene)-3-O-triisopropylsilyl-D-arabinohex-1-enitol-3,5-bis(benzyloxy)]-benzyl alcohol

Downstream raw materials:

C₃₃H₄₂O₉