Dichlorotetrakis(2-(2-pyridinyl)phenyl)diiridium(III)

Base Information

• Chemical Name: Dichlorotetrakis(2-(2-pyridinyl)phenyl)diiridium(III)
• CAS No.: 92220-65-0
• Molecular Formula: C₄₄H₃₂Cl₂Ir₂N₄
• Molecular Weight: 1072.11
• Hs Code.: 29319090
• European Community (EC) Number: 635-643-1
• Mol file: 92220-65-0.mol

Synonyms:[(ppy)2IrCl]2;Dichlorotetrakis(2-(2-pyridinyl)phenyl)diiridium(III);92220-65-0;603109-48-4;chloroiridium(2+);2-phenylpyridine;MFCD28144567;F16646;Di-?-chlorotetrakis[2-(2-pyridinyl-kN)phenyl-kC]diiridium(III)

Chemical Property of Dichlorotetrakis(2-(2-pyridinyl)phenyl)diiridium(III)

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 51.56000
• Density: g/cm³
• LogP: 12.37340
• Storage Temp.: Inert atmosphere,Room Temperature
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 4
• Exact Mass: 1070.12392
• Heavy Atom Count: 52
• Complexity: 535

Purity/Quality:

97% ^*data from raw suppliers

Dichlorotetrakis(2-(2-pyridinyl)phenyl)diiridium(III) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C([C-]=C1)C2=CC=CC=N2.C1=CC=C([C-]=C1)C2=CC=CC=N2.C1=CC=C([C-]=C1)C2=CC=CC=N2.C1=CC=C([C-]=C1)C2=CC=CC=N2.Cl[Ir+2].Cl[Ir+2]
• Uses: Dichlorotetrakis[2-(2-pyridyl)phenyl]diiridium(III) is useful in catalysis and OLEDs. Dichlorotetrakis(2-(2-pyridinyl)phenyl)diiridium(III) is used in the synthesis of electrochemical cells and luminescent compounds. Precursor for several OLED Iridium compounds. Has some use as a catalyst and in OLEDs.

Technology Process of Dichlorotetrakis(2-(2-pyridinyl)phenyl)diiridium(III)

There total 12 articles about Dichlorotetrakis(2-(2-pyridinyl)phenyl)diiridium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

2-phenylpyridine (1008-89-5) + iridium trichloride*(x)hydrate*(x)hydrochloride → [iridium(III)chloride(2-phenylpyridine)2]2 (1413974-24-9,1413974-25-0,338387-34-1,603109-48-4,92220-65-0,951813-16-4)

Guidance literature:

In not given; react. of Ir compound with ppy; chromd. (SiO2/CH2Cl2); elem. anal.;

DOI:10.1002/ejic.201100639

Reference yield: 79.0%

2-phenylpyridine (1008-89-5) + iridium(III) chloride trihydrate → [{Ir(2-phenylpyridine)2Cl}2] (1413974-24-9,1413974-25-0,338387-34-1,603109-48-4,92220-65-0,951813-16-4)

Guidance literature:

In 2-methoxy-ethanol; water;

DOI:10.1002/ejic.201201427

Reference yield: 63.9%

2-phenylpyridine (1008-89-5) + iridium(III) chloride n-hydrate → bis(2-phenylpyridinato)iridium(III) chloride dimer (1413974-24-9,1413974-25-0,338387-34-1,603109-48-4,92220-65-0,951813-16-4)

Guidance literature:

In 2-ethoxy-ethanol; water; for 24h; Reflux; Inert atmosphere;

upstream raw materials:

2-phenylpyridine

hydrogenchloride

Downstream raw materials:

[Ir(2-phenylpyridine)₂(5-(p-methoxyphenyl)-4,5-dipyrrin)]