2-(5-{[tert-Butyl(dimethyl)silyl]oxy}-2-methylidenecyclohexylidene)ethan-1-ol

Base Information

Chemical Name:2-(5-{[tert-Butyl(dimethyl)silyl]oxy}-2-methylidenecyclohexylidene)ethan-1-ol
CAS No.:96685-53-9
Molecular Formula:C15H28 O2 Si
Molecular Weight:268.472
Hs Code.:2931900090
DSSTox Substance ID:DTXSID70698433
Mol file:96685-53-9.mol

Synonyms:96685-53-9;SCHEMBL3212131;DTXSID70698433;2-[5-[tert-butyl(dimethyl)silyl]oxy-2-methylidenecyclohexylidene]ethanol;AKOS030255208;FT-0664062;2-(5-{[tert-Butyl(dimethyl)silyl]oxy}-2-methylidenecyclohexylidene)ethan-1-ol

Suppliers and Price of 2-(5-{[tert-Butyl(dimethyl)silyl]oxy}-2-methylidenecyclohexylidene)ethan-1-ol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(2Z)-2-[(5S)-O-tert-Butyldimethylsilyl-2-methylenecyclohexylidene]ethanol
100 mg
$ 290.00

Biosynth Carbosynth
(2Z)-2-[(5S)-O-tert-Butyldimethylsilyl-2-methylenecyclohexylidene]ethanol
500 mg
$ 1530.00

Biosynth Carbosynth
(2Z)-2-[(5S)-O-tert-Butyldimethylsilyl-2-methylenecyclohexylidene]ethanol
250 mg
$ 840.00

Biosynth Carbosynth
(2Z)-2-[(5S)-O-tert-Butyldimethylsilyl-2-methylenecyclohexylidene]ethanol
100 mg
$ 462.00

Biosynth Carbosynth
(2Z)-2-[(5S)-O-tert-Butyldimethylsilyl-2-methylenecyclohexylidene]ethanol
50 mg
$ 254.50

Biosynth Carbosynth
(2Z)-2-[(5S)-O-tert-Butyldimethylsilyl-2-methylenecyclohexylidene]ethanol
25 mg
$ 140.00

Total 12 raw suppliers

Chemical Property of 2-(5-{[tert-Butyl(dimethyl)silyl]oxy}-2-methylidenecyclohexylidene)ethan-1-ol

Chemical Property:

Vapor Pressure:0mmHg at 25°C
Refractive Index:1.476
Boiling Point:323.116°C at 760 mmHg
Flash Point:149.215°C
PSA：29.46000
Density:0.939g/cm³
LogP:4.03560
Solubility.:Dichloromethane, Ether, Ethyl Acetate,
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:268.185856666
Heavy Atom Count:18
Complexity:337

Purity/Quality:

99% ^*data from raw suppliers

(2Z)-2-[(5S)-O-tert-Butyldimethylsilyl-2-methylenecyclohexylidene]ethanol ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Si](C)(C)OC1CCC(=C)C(=CCO)C1

Technology Process of 2-(5-{[tert-Butyl(dimethyl)silyl]oxy}-2-methylidenecyclohexylidene)ethan-1-ol

There total 33 articles about 2-(5-{[tert-Butyl(dimethyl)silyl]oxy}-2-methylidenecyclohexylidene)ethan-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: [5-(tert-Butyl-dimethyl-silanyloxy)-2-methylene-cyclohex-(Z)-ylidene]-acetic acid methyl ester

: 96685-53-9,150255-38-2
2-[5-(tert-Butyl-dimethyl-silanyloxy)-2-methylene-cyclohex-(Z)-ylidene]-ethanol

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran;
DOI:10.1016/S0040-4039(00)93384-7

Reference yield: 86.0%

: (S,Z)-ethyl 2-(5-((tert-butyldimethylsilyl)oxy)-2-methylenecyclohexylidene)acetate

: 96685-53-9
(2Z)-2-<(5S)-5-(tert-butyldimethylsilyloxy)-2-methylene-cyclohexylidene>-ethanol

Guidance literature:: With diisobutylaluminium hydride; In tetrahydrofuran; dichloromethane; at -78 - 20 ℃; for 10h; Inert atmosphere;
DOI:10.1021/acs.orglett.5b02813

Reference yield: 83.0%

: 131852-63-6
(5Z,22E)-(7R)-3β-(tert-butyldimethylsilyloxy)-9,10-seco-8α-ergosta-5,10(19),22-triene-7,8-diol

: 55812-82-3,63730-57-4,63730-58-5,102281-42-5
(1R,3aR,4S,7aR)-7a-methyl-1-<(2E)-(1R,4R)-1,4,5-trimethyl-hex-2-enyl>-octahydro-1H-inden-4-ol

: 55812-80-1,55870-05-8,70144-73-9
(1R,3aR,7aR)-7a-Methyl-1-((E)-(1R,4R)-1,4,5-trimethyl-hex-2-enyl)-octahydro-inden-4-one

: 96685-53-9
(2Z)-2-<(5S)-5-(tert-butyldimethylsilyloxy)-2-methylene-cyclohexylidene>-ethanol

Guidance literature:: (5Z,22E)-(7R)-3β-(tert-butyldimethylsilyloxy)-9,10-seco-8α-ergosta-5,10(19),22-triene-7,8-diol; With pyridine; lead(IV) acetate; In dichloromethane; at 0 ℃; for 0.25h;

With sodium tetrahydroborate; cerium(III) chloride; In methanol; at 0 ℃; for 0.25h;
DOI:10.1055/s-1999-3530