p-chlorophenyl tri(3′-tert-butyldimethylsilyloxymethyl[4,1′]biphenyl)silane

Base Information

• Chemical Name: p-chlorophenyl tri(3′-tert-butyldimethylsilyloxymethyl[4,1′]biphenyl)silane
• CAS No.: 1428770-72-2
• Molecular Formula: C₆₃H₇₉ClO₃Si₄
• Molecular Weight: 1032.11
• Mol file: 1428770-72-2.mol

Synonyms:p-chlorophenyl tri(3′-tert-butyldimethylsilyloxymethyl[4,1′]biphenyl)silane

Chemical Property of p-chlorophenyl tri(3′-tert-butyldimethylsilyloxymethyl[4,1′]biphenyl)silane

Chemical Property:

Purity/Quality:

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Technology Process of p-chlorophenyl tri(3′-tert-butyldimethylsilyloxymethyl[4,1′]biphenyl)silane

There total 1 articles about p-chlorophenyl tri(3′-tert-butyldimethylsilyloxymethyl[4,1′]biphenyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

tri(4-iodophenyl)(4-chlorophenyl)silane (1428770-71-1) + 2-[3-({[(tert-butyl)(dimethyl)silyl]oxy}methyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (495402-49-8) → p-chlorophenyl tri(3′-tert-butyldimethylsilyloxymethyl[4,1′]biphenyl)silane (1428770-72-2)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; tetrabutylammomium bromide; potassium hydroxide; In methanol; toluene; at 85 ℃; for 12h; Inert atmosphere;

DOI:10.1016/j.tet.2013.02.054

Reference yield: 34.0%

1-phenyl-2-(4-(trifluoro-l4-boranyl)phenyl)diazene, potassium salt (931115-96-7) + p-chlorophenyl tri(3′-tert-butyldimethylsilyloxymethyl[4,1′]biphenyl)silane (1428770-72-2) → p-(4-azobenzene)phenyl tri(3′-tert-butyldimethylsilyloxymethyl[4,1′]biphenyl)silane (1428770-74-4)

Guidance literature:

With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate; potassium carbonate; In methanol; for 12h; Inert atmosphere; Reflux;

DOI:10.1016/j.tet.2013.02.054

upstream raw materials:

tri(4-iodophenyl)(4-chlorophenyl)silane

2-[3-({[(tert-butyl)(dimethyl)silyl]oxy}methyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Downstream raw materials:

p-(4-azobenzene)phenyl tri(3′-tert-butyldimethylsilyloxymethyl[4,1′]biphenyl)silane