4'-(4'-(pyridin-4-yl)-[1,1'-biphenyl]-4-yl)-[2,2':6',2]terpyridine

Base Information

• Chemical Name: 4'-(4'-(pyridin-4-yl)-[1,1'-biphenyl]-4-yl)-[2,2':6',2]terpyridine
• CAS No.: 1428944-86-8
• Molecular Formula: C₃₂H₂₂N₄
• Molecular Weight: 462.553
• Mol file: 1428944-86-8.mol

Synonyms:4'-(4'-(pyridin-4-yl)-[1,1'-biphenyl]-4-yl)-[2,2':6',2]terpyridine

Chemical Property of 4'-(4'-(pyridin-4-yl)-[1,1'-biphenyl]-4-yl)-[2,2':6',2]terpyridine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4'-(4'-(pyridin-4-yl)-[1,1'-biphenyl]-4-yl)-[2,2':6',2]terpyridine

There total 1 articles about 4'-(4'-(pyridin-4-yl)-[1,1'-biphenyl]-4-yl)-[2,2':6',2]terpyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

4′-(4′-bromo-[1,1′-biphenyl]-4-yl)-2,2′:6′,2″-terpyridine (1395098-19-7) + 4-pyridylboronic acid (1692-15-5) → 4'-(4'-(pyridin-4-yl)-[1,1'-biphenyl]-4-yl)-[2,2':6',2]terpyridine (1428944-86-8)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In 1,2-dimethoxyethane; water; for 24h; Reflux; Inert atmosphere;

DOI:10.1016/j.poly.2012.08.054

Reference yield: 92.0%

4'-(4'-(pyridin-4-yl)-[1,1'-biphenyl]-4-yl)-[2,2':6',2]terpyridine (1428944-86-8) + methyl iodide (74-88-4) → {[(2,2':6',2-terpyridin)-4'-yl]-[(1,1'-biphenyl)-4-yl]-1-methylpyridin-1-ium}

Guidance literature:

In acetonitrile;

DOI:10.1039/c4ra12749h

Reference yield:

cadmium(II) perchlorate hexahydrate + 4'-(4'-(pyridin-4-yl)-[1,1'-biphenyl]-4-yl)-[2,2':6',2]terpyridine (1428944-86-8) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → C64H44CdN8(2+)*2ClO4(1-)*2.8H2O*C3H7NO

Guidance literature:

at 100 ℃; for 2h;

DOI:10.1016/j.poly.2012.08.054

upstream raw materials:

4′-(4′-bromo-[1,1′-biphenyl]-4-yl)-2,2′:6′,2″-terpyridine

4-pyridylboronic acid