(3S,3aR,4R,6S,7R,8aR)-1-benzyl-3-(but-3-enyl)-7-((R)-1-(tertbutyldiphenylsilyloxy)ethyl)-6-(dimethyl(phenyl)silyl)-3a-methyl-4-vinyl-decahydrocyclohepta[b]pyrrol-4-ol

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Chemical Name:(3S,3aR,4R,6S,7R,8aR)-1-benzyl-3-(but-3-enyl)-7-((R)-1-(tertbutyldiphenylsilyloxy)ethyl)-6-(dimethyl(phenyl)silyl)-3a-methyl-4-vinyl-decahydrocyclohepta[b]pyrrol-4-ol
CAS No.:1198439-46-1
Molecular Formula:C₄₉H₆₅NO₂Si₂
Molecular Weight:756.232
Hs Code.:

(3S,3aR,4R,6S,7R,8aR)-1-benzyl-3-(but-3-enyl)-7-((R)-1-(tertbutyldiphenylsilyloxy)ethyl)-6-(dimethyl(phenyl)silyl)-3a-methyl-4-vinyl-decahydrocyclohepta[b]pyrrol-4-ol

Synonyms:(3S,3aR,4R,6S,7R,8aR)-1-benzyl-3-(but-3-enyl)-7-((R)-1-(tertbutyldiphenylsilyloxy)ethyl)-6-(dimethyl(phenyl)silyl)-3a-methyl-4-vinyl-decahydrocyclohepta[b]pyrrol-4-ol

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Chemical Property of (3S,3aR,4R,6S,7R,8aR)-1-benzyl-3-(but-3-enyl)-7-((R)-1-(tertbutyldiphenylsilyloxy)ethyl)-6-(dimethyl(phenyl)silyl)-3a-methyl-4-vinyl-decahydrocyclohepta[b]pyrrol-4-ol

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Technology Process of (3S,3aR,4R,6S,7R,8aR)-1-benzyl-3-(but-3-enyl)-7-((R)-1-(tertbutyldiphenylsilyloxy)ethyl)-6-(dimethyl(phenyl)silyl)-3a-methyl-4-vinyl-decahydrocyclohepta[b]pyrrol-4-ol

There total 1 articles about (3S,3aR,4R,6S,7R,8aR)-1-benzyl-3-(but-3-enyl)-7-((R)-1-(tertbutyldiphenylsilyloxy)ethyl)-6-(dimethyl(phenyl)silyl)-3a-methyl-4-vinyl-decahydrocyclohepta[b]pyrrol-4-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 1198439-41-6
(3S,3aR,6S,7R,8aR)-1-benzyl-3-(but-3-enyl)-7-((R)-1-(tertbutyldiphenylsilyloxy)ethyl)-6-(dimethyl(phenyl)silyl)-3a-methyloctahydrocyclohepta[b]pyrrol-4(5H)-one

: 1826-67-1
vinyl magnesium bromide

: 1198439-46-1
(3S,3aR,4R,6S,7R,8aR)-1-benzyl-3-(but-3-enyl)-7-((R)-1-(tertbutyldiphenylsilyloxy)ethyl)-6-(dimethyl(phenyl)silyl)-3a-methyl-4-vinyl-decahydrocyclohepta[b]pyrrol-4-ol

Guidance literature:: (3S,3aR,6S,7R,8aR)-1-benzyl-3-(but-3-enyl)-7-((R)-1-(tertbutyldiphenylsilyloxy)ethyl)-6-(dimethyl(phenyl)silyl)-3a-methyloctahydrocyclohepta[b]pyrrol-4(5H)-one; With cerium(III) chloride bis(lithium chloride); In tetrahydrofuran; at -78 - 25 ℃; Inert atmosphere;

vinyl magnesium bromide; In tetrahydrofuran; at -78 ℃; for 0.333333h; Inert atmosphere;

With acetic acid; In tetrahydrofuran; methanol; diethyl ether; water; at -78 - 25 ℃; Inert atmosphere;
DOI:10.1021/ol902373m

Reference yield: 96.0%

: 1198439-46-1
(3S,3aR,4R,6S,7R,8aR)-1-benzyl-3-(but-3-enyl)-7-((R)-1-(tertbutyldiphenylsilyloxy)ethyl)-6-(dimethyl(phenyl)silyl)-3a-methyl-4-vinyl-decahydrocyclohepta[b]pyrrol-4-ol

: 1198439-47-2
C₄₇H₆₁NO₂Si₂

Guidance literature:: With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; for 2.5h; Inert atmosphere; Reflux;
DOI:10.1021/ol902373m