Cyclopropanecarboxylic acid, 2-ethenyl-2-methyl-, methyl ester, trans- (9CI)

Base Information

• Chemical Name: Cyclopropanecarboxylic acid, 2-ethenyl-2-methyl-, methyl ester, trans- (9CI)
• CAS No.: 96358-61-1
• Molecular Formula: C₈H₁₂O₂
• Molecular Weight: 140.182
• Mol file: 96358-61-1.mol

Synonyms:Cyclopropanecarboxylicacid, 2-ethenyl-2-methyl-, methyl ester, trans- (9CI)

Chemical Property of Cyclopropanecarboxylic acid, 2-ethenyl-2-methyl-, methyl ester, trans- (9CI)

Chemical Property:

• PSA: 26.30000
• LogP: 1.37160

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cyclopropanecarboxylic acid, 2-ethenyl-2-methyl-, methyl ester, trans- (9CI)

There total 4 articles about Cyclopropanecarboxylic acid, 2-ethenyl-2-methyl-, methyl ester, trans- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 9.0%

methyl diazoacetate (6832-16-2) + isoprene (78-79-5,9003-31-0) → (1R,2S)-2-Methyl-2-vinyl-cyclopropanecarboxylic acid methyl ester (14027-57-7,96358-59-7,96358-61-1) + (1R,2R)-2-Methyl-2-vinyl-cyclopropanecarboxylic acid methyl ester (14027-57-7,96358-59-7,96358-61-1) + 1,4-dimethyl but-2-enedioate (23055-10-9)

Guidance literature:

With 2,6-dimethylpyridine; copper diacetate; zinc(II) chloride; In dichloromethane; at 40 ℃; regioselective reaction;

DOI:10.1007/s11172-008-0238-x

Reference yield: 9.0%

methyl diazoacetate (6832-16-2) + isoprene (78-79-5,9003-31-0) → (1R,2S)-2-Methyl-2-vinyl-cyclopropanecarboxylic acid methyl ester (14027-57-7,96358-59-7,96358-61-1) + (1R,2R)-2-Methyl-2-vinyl-cyclopropanecarboxylic acid methyl ester (14027-57-7,96358-59-7,96358-61-1) + 1,4-dimethyl but-2-enedioate (23055-10-9)

Guidance literature:

With 2,6-dimethylpyridine; copper diacetate; zinc(II) chloride; In dichloromethane; at 40 ℃; regioselective reaction;

DOI:10.1007/s11172-008-0238-x

Reference yield:

methyl diazoacetate (6832-16-2) + isoprene (78-79-5,9003-31-0) → (1R,2S)-2-Isopropenyl-cyclopropanecarboxylic acid methyl ester (15143-59-6,52148-73-9,67500-46-3,96358-64-4) + trans-2-Isopropenyl-cyclopropan-carbonsaeure-methylester (15143-59-6,52148-73-9,67500-46-3,96358-64-4) + (1R,2S)-2-Methyl-2-vinyl-cyclopropanecarboxylic acid methyl ester (14027-57-7,96358-59-7,96358-61-1) + (1R,2R)-2-Methyl-2-vinyl-cyclopropanecarboxylic acid methyl ester (14027-57-7,96358-59-7,96358-61-1)

Guidance literature:

L(+)-2-(tetrachlorophthalimido) propionato-Rh(II); at 22 ℃; for 4h; Yield given. Yields of byproduct given;

upstream raw materials:

methyl diazoacetate

isoprene

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

✦Write with AI

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 96358-61-1 Cyclopropanecarboxylic acid, 2-ethenyl-2-methyl-, methyl ester, trans- (9CI)

Send

Send

Metric Ton KG G Pound L ML

Send

Send