(1R,2R,3R)-2,6-dimethylphenyl 2-methyl-3-phenylcyclopropanecarboxylate

Base Information

• Chemical Name: (1R,2R,3R)-2,6-dimethylphenyl 2-methyl-3-phenylcyclopropanecarboxylate
• CAS No.: 1404433-40-4
• Molecular Formula: C₁₉H₂₀O₂
• Molecular Weight: 280.367
• Mol file: 1404433-40-4.mol

Synonyms:(1R,2R,3R)-2,6-dimethylphenyl 2-methyl-3-phenylcyclopropanecarboxylate

Chemical Property of (1R,2R,3R)-2,6-dimethylphenyl 2-methyl-3-phenylcyclopropanecarboxylate

Chemical Property:

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Technology Process of (1R,2R,3R)-2,6-dimethylphenyl 2-methyl-3-phenylcyclopropanecarboxylate

There total 1 articles about (1R,2R,3R)-2,6-dimethylphenyl 2-methyl-3-phenylcyclopropanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

1-propenylbenzene (873-66-5) + 2,6-dimethylphenyl 2-diazoacetate (131833-94-8) → (1R,2R,3R)-2,6-dimethylphenyl 2-methyl-3-phenylcyclopropanecarboxylate (1404433-40-4)

Guidance literature:

With C₂₇H₂₆N₂O₂; copper(I) triflate; In 2-methylpropyl acetate; at 30 ℃; for 8h; optical yield given as %de; diastereoselective reaction; Inert atmosphere; Molecular sieve;

DOI:10.1002/anie.201203218

upstream raw materials:

1-propenylbenzene

2,6-dimethylphenyl 2-diazoacetate