cis-tetracarbonyl[((Z)-η2-N-allyl-N-methylamino)(p-tolyl)carbene]tungsten(0)

Base Information

Chemical Name:cis-tetracarbonyl[((Z)-η2-N-allyl-N-methylamino)(p-tolyl)carbene]tungsten(0)
CAS No.:90245-85-5
Molecular Formula:C₁₆H₁₅NO₄W
Molecular Weight:469.149
Hs Code.:

Synonyms:cis-tetracarbonyl[((Z)-η2-N-allyl-N-methylamino)(p-tolyl)carbene]tungsten(0)

Suppliers and Price of cis-tetracarbonyl[((Z)-η2-N-allyl-N-methylamino)(p-tolyl)carbene]tungsten(0)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of cis-tetracarbonyl[((Z)-η2-N-allyl-N-methylamino)(p-tolyl)carbene]tungsten(0)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of cis-tetracarbonyl[((Z)-η2-N-allyl-N-methylamino)(p-tolyl)carbene]tungsten(0)

There total 1 articles about cis-tetracarbonyl[((Z)-η2-N-allyl-N-methylamino)(p-tolyl)carbene]tungsten(0) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 77310-69-1
(CO)4WCC₆H₄CH₃(NHCH₂CHCH₂)

: 4111-54-0
lithium diisopropyl amide

: 90245-85-5
cis-tetracarbonyl[((Z)-η2-N-allyl-N-methylamino)(p-tolyl)carbene]tungsten(0)

Guidance literature:: With CH₃I; In tetrahydrofuran; a soln. of lithium diisopropylamide in THF was added to soln. of W-complex in THF at -72°C, soln. was warmed to room temp., cooled back to -72°C and CH3I was added, soln. was warmed to room temp. underN2; preparative TLC (silica gel, CH2Cl2-hexane) gave solid ppt.;
DOI:10.1021/ja00325a008