(Z)-2-((tert-butyldimethylsilyl)oxy)-1-(1-phenyl-1H-imidazol-2-yl)vinyl cyclohex-2-en-1-yl carbonate

Base Information

Chemical Name:(Z)-2-((tert-butyldimethylsilyl)oxy)-1-(1-phenyl-1H-imidazol-2-yl)vinyl cyclohex-2-en-1-yl carbonate
CAS No.:1233735-69-7
Molecular Formula:C₂₄H₃₂N₂O₄Si
Molecular Weight:440.615
Hs Code.:

Synonyms:(Z)-2-((tert-butyldimethylsilyl)oxy)-1-(1-phenyl-1H-imidazol-2-yl)vinyl cyclohex-2-en-1-yl carbonate

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Chemical Property of (Z)-2-((tert-butyldimethylsilyl)oxy)-1-(1-phenyl-1H-imidazol-2-yl)vinyl cyclohex-2-en-1-yl carbonate

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Technology Process of (Z)-2-((tert-butyldimethylsilyl)oxy)-1-(1-phenyl-1H-imidazol-2-yl)vinyl cyclohex-2-en-1-yl carbonate

There total 1 articles about (Z)-2-((tert-butyldimethylsilyl)oxy)-1-(1-phenyl-1H-imidazol-2-yl)vinyl cyclohex-2-en-1-yl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 1233735-47-1
2-hydroxy-1-(1-phenyl-1H-imidazol-2-yl)ethanone

: 18162-48-6
tert-butyldimethylsilyl chloride

: 141037-04-9
cyclohex-2-en-1-yl 1H-imidazole-1-carboxylate

: 1233735-69-7
(Z)-2-((tert-butyldimethylsilyl)oxy)-1-(1-phenyl-1H-imidazol-2-yl)vinyl cyclohex-2-en-1-yl carbonate

Guidance literature:: 2-hydroxy-1-(1-phenyl-1H-imidazol-2-yl)ethanone; With sodium hexamethyldisilazane; In tetrahydrofuran; at -78 - 0 ℃; Inert atmosphere;

cyclohex-2-en-1-yl 1H-imidazole-1-carboxylate; In tetrahydrofuran; at -78 ℃; for 1h; Inert atmosphere;

tert-butyldimethylsilyl chloride; In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere;
DOI:10.1021/ja103771w

Reference yield:

: 1233735-69-7
(Z)-2-((tert-butyldimethylsilyl)oxy)-1-(1-phenyl-1H-imidazol-2-yl)vinyl cyclohex-2-en-1-yl carbonate

: 1233735-88-0
(2S)-2-((tert-butyldimethylsilyl)oxy)-2-(cyclohex-2-en-1-yl)-1-(1-phenyl-1H-imidazol-2-yl)ethanone

Guidance literature:: With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; (1R,2R)-1,2-bis[(2-diphenylphosphanyl)benzoylamino]cyclohexane; In 1,4-dioxane; at 20 ℃; for 16h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ja103771w