4-[1-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-benzoic acid methyl ester

Base Information

Chemical Name:4-[1-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-benzoic acid methyl ester
CAS No.:935559-76-5
Molecular Formula:C₁₈H₂₈O₃Si
Molecular Weight:320.504
Hs Code.:

Synonyms:4-[1-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-benzoic acid methyl ester

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Chemical Property of 4-[1-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-benzoic acid methyl ester

Chemical Property:

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Technology Process of 4-[1-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-benzoic acid methyl ester

There total 3 articles about 4-[1-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-benzoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 329796-89-6
(S)-4-(1-hydroxy-but-3-enyl)-benzoic acid methyl ester

: 935559-76-5
4-[1-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-benzoic acid methyl ester

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃; for 1h;
DOI:10.1021/ol063026p

Reference yield:

: 6908-41-4,58590-49-1
4-(methoxycarbonyl)benzyl alcohol

: 935559-76-5
4-[1-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-benzoic acid methyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: MnO₂ / CH₂Cl₂ / 24 h / 20 °C

2.1: diethyl ether; CH₂Cl₂ / -100 °C

2.2: NaOH; H₂O₂ / diethyl ether; CH₂Cl₂; H₂O / Heating

3.1: imidazole / dimethylformamide / 1 h / 20 °C

With 1H-imidazole; manganese(IV) oxide; In diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ol063026p

Reference yield:

: 1571-08-0
methyl 4-formylbenzoate

: 935559-76-5
4-[1-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-benzoic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: diethyl ether; CH₂Cl₂ / -100 °C

1.2: NaOH; H₂O₂ / diethyl ether; CH₂Cl₂; H₂O / Heating

2.1: imidazole / dimethylformamide / 1 h / 20 °C

With 1H-imidazole; In diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ol063026p