6,7-dideoxy-2-O-phenoxycarbonyl-5-O-[3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroacetamido)-β-D-glucopyranosyl]-L-galacto-hept-6-enono-1,4-lactone

Base Information

Chemical Name:6,7-dideoxy-2-O-phenoxycarbonyl-5-O-[3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroacetamido)-β-D-glucopyranosyl]-L-galacto-hept-6-enono-1,4-lactone
CAS No.:403709-34-2
Molecular Formula:C₂₈H₃₀Cl₃NO₁₅
Molecular Weight:726.903
Hs Code.:

Synonyms:6,7-dideoxy-2-O-phenoxycarbonyl-5-O-[3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroacetamido)-β-D-glucopyranosyl]-L-galacto-hept-6-enono-1,4-lactone

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Chemical Property of 6,7-dideoxy-2-O-phenoxycarbonyl-5-O-[3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroacetamido)-β-D-glucopyranosyl]-L-galacto-hept-6-enono-1,4-lactone

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Technology Process of 6,7-dideoxy-2-O-phenoxycarbonyl-5-O-[3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroacetamido)-β-D-glucopyranosyl]-L-galacto-hept-6-enono-1,4-lactone

There total 5 articles about 6,7-dideoxy-2-O-phenoxycarbonyl-5-O-[3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroacetamido)-β-D-glucopyranosyl]-L-galacto-hept-6-enono-1,4-lactone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 1885-14-9
phenyl chloroformate

: 403709-32-0
6,7-dideoxy-5-O-[3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroacetamido)-β-D-glucopyranosyl]-L-galacto-hept-6-enono-1,4-lactone

: 403709-34-2
6,7-dideoxy-2-O-phenoxycarbonyl-5-O-[3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroacetamido)-β-D-glucopyranosyl]-L-galacto-hept-6-enono-1,4-lactone

Guidance literature:: With pyridine; In dichloromethane; at -20 ℃; for 2h;
DOI:10.1016/S0040-4020(01)00951-6

Reference yield:

: 161545-19-3
3,4,6-tri-O-acetyl-2-deoxy-2-trichloroacetamido-α/β-D-glucopyranose trichloroacetimidate

: 403709-34-2
6,7-dideoxy-2-O-phenoxycarbonyl-5-O-[3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroacetamido)-β-D-glucopyranosyl]-L-galacto-hept-6-enono-1,4-lactone

Guidance literature:: Multi-step reaction with 3 steps

1.1: acetonitrile / 1 h / 20 °C

1.2: trimethylsilyl triflate / acetonitrile / 6 h / -20 °C

2.1: 94 percent / CuCl₂*2H₂O / acetonitrile / 5 h / Heating

3.1: 70 percent / pyridine / CH₂Cl₂ / 2 h / -20 °C

With pyridine; In dichloromethane; acetonitrile;
DOI:10.1016/S0040-4020(01)00951-6

Reference yield:

: 342896-38-2
5-O-[3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroacetamido)-β-D-glucopyranosyl]-6,7-dideoxy-2,3-O-isopropylidene-L-galacto-hept-6-enonamide

: 403709-34-2
6,7-dideoxy-2-O-phenoxycarbonyl-5-O-[3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroacetamido)-β-D-glucopyranosyl]-L-galacto-hept-6-enono-1,4-lactone

Guidance literature:: Multi-step reaction with 2 steps

1: 94 percent / CuCl₂*2H₂O / acetonitrile / 5 h / Heating

2: 70 percent / pyridine / CH₂Cl₂ / 2 h / -20 °C

With pyridine; In dichloromethane; acetonitrile;
DOI:10.1016/S0040-4020(01)00951-6