Meldrum's acid anion

Base Information

• Chemical Name: Meldrum's acid anion
• CAS No.: 12256-88-1
• Molecular Formula: C₆H₇O₄
• Molecular Weight: 143.119

Synonyms:Meldrum's acid anion

Chemical Property of Meldrum's acid anion

Chemical Property:

Purity/Quality:

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Technology Process of Meldrum's acid anion

There total 2 articles about Meldrum's acid anion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C15H17N2O5(1-)*H(1+) → Meldrum's acid anion (12256-88-1) + benzaldehyde (100-52-7)

Guidance literature:

In water; water-d2; at 25 ℃; Rate constant;

DOI:10.1021/ja00245a036

Reference yield:

morpholine (110-91-8,99108-56-2) + 5-benzylidene Meldrum's acid (1214-54-6) → Meldrum's acid anion (12256-88-1) + benzaldehyde (100-52-7)

Guidance literature:

In water; at 25 ℃; Kinetics; different pH;

DOI:10.1021/ja00536a035

Reference yield: 73.0%

(+/-)-(1,3/2,4)-1,2,3,4-tetra-O-acetyl-5-cyclohexene-1,2,3,4-tetrol (4381-96-8,6216-24-6,25348-63-4,80226-74-0,109526-05-8,123354-99-4,123355-00-0,123355-01-1,129829-60-3,129829-61-4,133319-96-7,143615-78-5,143615-79-6) + Meldrum's acid anion (12256-88-1) → Acetic acid (1S,2S,5R,6S)-5,6-diacetoxy-2-(2,2-dimethyl-4,6-dioxo-[1,3]dioxan-5-yl)-cyclohex-3-enyl ester (135346-51-9)

Guidance literature:

(PH₃P)Pd; In N,N-dimethyl-formamide; at 70 ℃;

DOI:10.1016/S0040-4039(00)74357-7

upstream raw materials:

morpholine

5-benzylidene Meldrum's acid

Downstream raw materials:

Acetic acid (1S,2S,5R,6S)-5,6-diacetoxy-2-(2,2-dimethyl-4,6-dioxo-[1,3]dioxan-5-yl)-cyclohex-3-enyl ester

succinimide anion

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