5-[N,N-bis(phenylamino)phenyl]-5'-formyl-3,3'-diphenylsilylene-2,2'-bithiophene

Base Information

• Chemical Name: 5-[N,N-bis(phenylamino)phenyl]-5'-formyl-3,3'-diphenylsilylene-2,2'-bithiophene
• CAS No.: 1235485-13-8
• Molecular Formula: C₃₉H₂₇NOS₂Si
• Molecular Weight: 617.867
• Mol file: 1235485-13-8.mol

Synonyms:5-[N,N-bis(phenylamino)phenyl]-5'-formyl-3,3'-diphenylsilylene-2,2'-bithiophene

Chemical Property of 5-[N,N-bis(phenylamino)phenyl]-5'-formyl-3,3'-diphenylsilylene-2,2'-bithiophene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of 5-[N,N-bis(phenylamino)phenyl]-5'-formyl-3,3'-diphenylsilylene-2,2'-bithiophene

There total 1 articles about 5-[N,N-bis(phenylamino)phenyl]-5'-formyl-3,3'-diphenylsilylene-2,2'-bithiophene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

5-[N,N-bis(phenylamino)phenyl]-3,3'-diphenylsilylene-2,2'-bithiophene (1235485-09-2) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → 5-[N,N-bis(phenylamino)phenyl]-5'-formyl-3,3'-diphenylsilylene-2,2'-bithiophene (1235485-13-8)

Guidance literature:

With trichlorophosphate; at -40 - 60 ℃; Inert atmosphere;

DOI:10.1021/jo100762t

Reference yield: 85.0%

5-[N,N-bis(phenylamino)phenyl]-5'-formyl-3,3'-diphenylsilylene-2,2'-bithiophene (1235485-13-8) + cyanoacetic acid (372-09-8) → 3-[5-[N,N-bis(phenylamino)phenyl]-3,3'-diphenylsilylene-2,2'-bithiophene-5'-yl]-2-cyanoacrylic acid (1235485-17-2)

Guidance literature:

With ammonium acetate; In acetic acid; at 120 ℃; for 12h; Inert atmosphere;

DOI:10.1021/jo100762t

Reference yield: 72.0%

5-[N,N-bis(phenylamino)phenyl]-5'-formyl-3,3'-diphenylsilylene-2,2'-bithiophene (1235485-13-8) + malononitrile (109-77-3) → 5-[N,N-bis(phenylamino)phenyl]-5'-dicyanomethylidenemethyl-3,3'-diphenylsilylene-2,2'-bithiophene (1321562-79-1)

Guidance literature:

With aluminum oxide; In toluene; at 70 ℃; for 1h; Inert atmosphere;

DOI:10.1039/c1cc12139a

upstream raw materials:

5-[N,N-bis(phenylamino)phenyl]-3,3'-diphenylsilylene-2,2'-bithiophene

N,N-dimethyl-formamide

Downstream raw materials:

3-[5-[N,N-bis(phenylamino)phenyl]-3,3'-diphenylsilylene-2,2'-bithiophene-5'-yl]-2-cyanoacrylic acid

5-[N,N-bis(phenylamino)phenyl]-5'-dicyanomethylidenemethyl-3,3'-diphenylsilylene-2,2'-bithiophene