C₂₆H₃₆O₄Si

Base Information

• Chemical Name: C₂₆H₃₆O₄Si
• CAS No.: 1429412-40-7
• Molecular Formula: C₂₆H₃₆O₄Si
• Molecular Weight: 440.655
• Mol file: 1429412-40-7.mol

Synonyms:C₂₆H₃₆O₄Si

Chemical Property of C₂₆H₃₆O₄Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of C₂₆H₃₆O₄Si

There total 9 articles about C₂₆H₃₆O₄Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

C25H34O4Si (1429412-39-4) + methyl iodide (74-88-4) → C26H36O4Si (1429412-40-7)

Guidance literature:

With silver(l) oxide; In diethyl ether; for 1h; Molecular sieve; Reflux;

DOI:10.1039/c3ob27508f

Reference yield: 78.0%

C26H34O4Si (1429412-41-8) → C26H36O4Si (1429412-40-7)

Guidance literature:

With hydrogen; In isopropyl alcohol; at 20 ℃; for 6h;

DOI:10.1039/c3ob27508f

Reference yield:

3-((tert-butyldiphenylsilyl)oxy)-2,2-dimethylpropan-1-ol (147509-22-6) → C26H36O4Si (1429412-40-7)

Guidance literature:

Multi-step reaction with 5 steps

1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / ethyl acetate / 6 h / Reflux

2: (R)-Tol-BINAP; tetrabutylammonium triphenyldifluorosilicate; copper(II) bis(trifluoromethanesulfonate) / tetrahydrofuran / 16 h / -78 °C

3: methanol; toluene / 1 h / 110 °C / Sealed tube

4: potassium carbonate / acetone / 5 h

5: hydrogen / isopropyl alcohol / 6 h / 20 °C

With (R)-Tol-BINAP; hydrogen; copper(II) bis(trifluoromethanesulfonate); potassium carbonate; tetrabutylammonium triphenyldifluorosilicate; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; methanol; ethyl acetate; isopropyl alcohol; acetone; toluene; 2: |Mukaiyama Aldol Addition;

DOI:10.1039/c3ob27508f

upstream raw materials:

C₂₈H₃₈O₅Si

C₂₆H₃₆O₅Si

2,2-Dimethyl-1,3-propanediol

C₂₆H₃₈O₅Si

Downstream raw materials:

C₄₆H₇₂O₅Si₂

C₄₆H₇₂O₅Si₂

C₄₅H₆₆O₅Si₂

C₃₄H₅₇NO₅Si₂