(η2-trans-cyclooctene)2Fe(CO)3

Base Information

Chemical Name:(η2-trans-cyclooctene)2Fe(CO)3
CAS No.:115224-73-2
Molecular Formula:C₁₉H₂₈FeO₃
Molecular Weight:360.277
Hs Code.:

Synonyms:(η2-trans-cyclooctene)2Fe(CO)3

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Chemical Property of (η2-trans-cyclooctene)2Fe(CO)3

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Technology Process of (η2-trans-cyclooctene)2Fe(CO)3

There total 1 articles about (η2-trans-cyclooctene)2Fe(CO)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.4%

: 135759-58-9,115224-75-4,115224-76-5,88657-71-0,115224-73-2
tricarbonylbis(cis-cyclooctene)iron

: 931-89-5,25267-51-0
(E)-cyclooctene

: 931-88-4,931-87-3,25267-51-0
cis-Cyclooctene

: 115224-75-4
(η2-trans-cyclooctene)2Fe(CO)3

: 115224-73-2
(η2-trans-cyclooctene)2Fe(CO)3

Guidance literature:: In diethyl ether; stirring, warming from -78°C to ambient temp.; cooling to -30°C yields one enantiomer (filtn., drying in vacuo), cooling to -78°C or evaporation of mother liquor yields mixtures of enantiomers, which could be sepd. by repeated recrystn. from hexane and/or diethyl ether; elem. anal.;

Reference yield: 86.7%

: 115224-73-2,115224-75-4,115224-76-5,135759-58-9,88657-71-0
Fe(CO)3(cis-cyclooctene)2

: 983-80-2
cis-1,2-bis-(diphenylphosphino)ethene

: 21044-40-6
(cis-(bis(diphenylphosphino)ethylene))tricarbonyliron(O)

Guidance literature:: In tetrahydrofuran; stirring soln. of Fe complex in THF for 10 min at -60°C under N2; dropwise addn. of soln. of ligand in THF; storage for 2 h at -60°C; warming to room temp.;; filtration; evapn. to dryness under vac.; washing with n-hexane;;

Reference yield: 85.0%

: 115224-73-2,115224-75-4,115224-76-5,135759-58-9,88657-71-0
(η(2)-cyclooctene)2Fe(CO)3

: 123332-69-4
5,11,17,23-tetra(tert-butyl)-25,26,27,28-tetra(diphenylphosphinooxy)calix[4]arene

: (Fe(CO)3)2{CH₂C₆H₂(C(CH₃)3)(OP(C₆H₅)2)}4*2C₆H₆

Guidance literature:: With benzene; In hexane; byproducts: cyclooctene; cooling ligand suspension to -60°C; addn. of cyclooctene; addn. of Fe complex at -60°C; slowly heating to room temp.; reacting at -30°C.; pptn.; stirring, room temp., 24h; drying solid, 40°C; crystn. from benzene; elem. anal.;
DOI:10.1039/DT9930000813