[RuH(OSO₂CF₃)(C₇H₈)(P(C₆H₅)3)2]

Base Information

• Chemical Name: [RuH(OSO₂CF₃)(C₇H₈)(P(C₆H₅)3)2]
• CAS No.: 308366-36-1
• Molecular Formula: C₄₄H₃₉F₃O₃P₂RuS
• Molecular Weight: 867.871
• Mol file: 308366-36-1.mol

Synonyms:[RuH(OSO₂CF₃)(C₇H₈)(P(C₆H₅)3)2]

Chemical Property of [RuH(OSO₂CF₃)(C₇H₈)(P(C₆H₅)3)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [RuH(OSO₂CF₃)(C₇H₈)(P(C₆H₅)3)2]

There total 3 articles about [RuH(OSO₂CF₃)(C₇H₈)(P(C₆H₅)3)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

RuHCl(C7H8)(P(C6H5)3)2 (12392-83-5,89395-73-3) + silver trifluoromethanesulfonate (2923-28-6) → [RuH(OSO2CF3)(C7H8)(P(C6H5)3)2] (308366-36-1)

Guidance literature:

In tetrahydrofuran; (N2); standard Schlenk technique; mixt. of Ru complex and AgOTf in THF stirred for 0.5 h; solvent removed in vac.; aq. MeOH added; filtered; washed (water); dried in vac. for 3 h; extd. (benzene/hexane, 8/1); filtered through Celite column; concd.; hexane added; filtered; washed (hexane); dried (vac.); elem. anal.;

DOI:10.1021/om000369x

Reference yield:

RuHCl(C7H8)(P(C6H5)3)2 (12392-83-5,89395-73-3) + trifluorormethanesulfonic acid (1493-13-6) → [Ru(P(C6H5)3)2Cl2]2 + RuHCF3SO3(P(C6H5)3)2C7H8 (308366-36-1)

Guidance literature:

In benzene-d6; byproducts: norbornene; to NMR tube charged with Ru-complex and C6D6 was added ligand, allowed to stand for 1 h under N2; monitored by NMR;

DOI:10.1021/om010029r

Reference yield:

RuHCl(C7H8)(P(C6H5)3)2 (12392-83-5,89395-73-3) + trifluorormethanesulfonic acid (1493-13-6) → RuHCF3SO3(P(C6H5)3)2C7H8 (308366-36-1) + Ru3Cl5(P(C6H5)3)6(1+)*CF3SO3(1-)=Ru3Cl5(P(C6H5)3)6CF3SO3

Guidance literature:

In dichloromethane-d2; byproducts: norbornene; to NMR tube charged with Ru-complex and CD2Cl2 was added ligand, allowedto stand for 5 h under N2; monitored by NMR;

DOI:10.1021/om010029r

upstream raw materials:

RuHCl(C₇H₈)(P(C₆H₅)3)2

silver trifluoromethanesulfonate

trifluorormethanesulfonic acid

Downstream raw materials:

[RuH(C₆H₆)(P(C₆H₅)3)2]⁽¹⁺⁾*CF₃SO₃^(1-)=[RuH(C₆H₆)(P(C₆H₅)3)2](CF₃SO₃)

RuHCH₃CN(P(C₆H₅)3)2C₇H₈⁽¹⁺⁾*B(C₆H₅)4^(1-)=RuHCH₃CN(P(C₆H₅)3)2C₇H₈B(C₆H₅)4

[RuH(C₆D₆)(P(C₆H₅)3)2]⁽¹⁺⁾*OSO₂CF₃^(1-)=[RuH(C₆D₆)(P(C₆H₅)3)2]OSO₂CF₃

[RuH(P(C₆H₅)3)4]⁽¹⁺⁾*OSO₂CF₃^(1-)=[RuH(P(C₆H₅)3)4]OSO₂CF₃