Methyl (2R,4R,5S,6R)-6-(diphenoxyphosphoryloxymethyl)-4,5-dihydroxy-2-methoxyoxane-2-carboxylate

Base Information

Chemical Name:Methyl (2R,4R,5S,6R)-6-(diphenoxyphosphoryloxymethyl)-4,5-dihydroxy-2-methoxyoxane-2-carboxylate
CAS No.:91382-79-5
Molecular Formula:C₂₁H₂₅O₁₀P
Molecular Weight:468.397
Hs Code.:
DSSTox Substance ID:DTXSID90454093
Wikidata:Q82275428
Mol file:91382-79-5.mol

Synonyms:91382-79-5;Methyl (2R,4R,5S,6R)-6-(diphenoxyphosphoryloxymethyl)-4,5-dihydroxy-2-methoxyoxane-2-carboxylate;Methyl (Methyl 3-Deoxy-D-arabino-heptulopyranosid)onate-7-(diphenyl Phosphate);Methyl (methyl 3-deoxy-D-arabino-hept-2-ulopyranosid)onate-7-(diphenyl phosphate;DTXSID90454093;ZPKHHOXWTUSRFI-WERVVEIQSA-N;AKOS030254366;Methyl (methyl 3-deoxy-D-arabino-hept-2-ulopyranosid)onate-7-(diphenyl phosphate);W-204059;Dimethyl 3-deoxy-7-O-(diphenoxyphosphoryl)-alpha-D-arabino-hept-2-ulopyranosidonate

Suppliers and Price of Methyl (2R,4R,5S,6R)-6-(diphenoxyphosphoryloxymethyl)-4,5-dihydroxy-2-methoxyoxane-2-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Methyl(Methyl3-Deoxy-D-arabino-heptulopyranosid)onate-7-(diphenylPhosphate)
10mg
$ 250.00

Biosynth Carbosynth
Methyl (methyl 3-deoxy-D-arabino-hept-2-ulopyranosid)onate-7-(diphenyl phosphate)
50 mg
$ 1102.50

Biosynth Carbosynth
Methyl (methyl 3-deoxy-D-arabino-hept-2-ulopyranosid)onate-7-(diphenyl phosphate)
25 mg
$ 840.00

Biosynth Carbosynth
Methyl (methyl 3-deoxy-D-arabino-hept-2-ulopyranosid)onate-7-(diphenyl phosphate)
10 mg
$ 525.00

AK Scientific
Methyl(2R,4R,5S,6R)-6-(diphenoxyphosphoryloxymethyl)-4,5-dihydroxy-2-methoxyoxane-2-carboxylate
50mg
$ 1538.00

Total 4 raw suppliers

Chemical Property of Methyl (2R,4R,5S,6R)-6-(diphenoxyphosphoryloxymethyl)-4,5-dihydroxy-2-methoxyoxane-2-carboxylate

Chemical Property:

PSA：139.79000
LogP:2.29550
XLogP3:1.7
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:10
Rotatable Bond Count:10
Exact Mass:468.11853399
Heavy Atom Count:32
Complexity:625

Purity/Quality:

95% ^*data from raw suppliers

Methyl(Methyl3-Deoxy-D-arabino-heptulopyranosid)onate-7-(diphenylPhosphate) ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1(CC(C(C(O1)COP(=O)(OC2=CC=CC=C2)OC3=CC=CC=C3)O)O)OC
Isomeric SMILES:COC(=O)[C@]1(C[C@H]([C@@H]([C@H](O1)COP(=O)(OC2=CC=CC=C2)OC3=CC=CC=C3)O)O)OC
Uses Methyl (Methyl 3-Deoxy-D-arabino-heptulopyranosid)onate-7-(diphenyl Phosphate) (cas# 91382-79-5) is a compound useful in organic synthesis.

Technology Process of Methyl (2R,4R,5S,6R)-6-(diphenoxyphosphoryloxymethyl)-4,5-dihydroxy-2-methoxyoxane-2-carboxylate

There total 4 articles about Methyl (2R,4R,5S,6R)-6-(diphenoxyphosphoryloxymethyl)-4,5-dihydroxy-2-methoxyoxane-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 2880-95-7,85549-51-5
methyl (methyl 3-deoxy-α-D-arabino-2-heptulopyranosid)onate

: 2524-64-3
chlorophosphoric acid diphenyl ester

: 90318-58-4,91382-79-5
diphenyl 7-phosphate

Guidance literature:: In pyridine; at -20 ℃; for 0.5h;
DOI:10.1016/S0008-6215(96)00227-3

Reference yield: 84.0%

: 2880-95-7,85549-51-5
methyl (methyl 3-deoxy-α-D-arabino-2-heptulopyranosid)onate

: 1499-21-4
Diphenylphosphinic chloride

: 90318-58-4,91382-79-5
diphenyl 7-phosphate

Guidance literature:: In pyridine; benzene; -10 deg.C to room temp;
DOI:10.1016/0008-6215(84)85101-0

Reference yield:

: 85464-51-3
(2R,4R,5S,6R)-4,5-Diacetoxy-6-acetoxymethyl-2-methoxy-tetrahydro-pyran-2-carboxylic acid methyl ester

: 90318-58-4,91382-79-5
diphenyl 7-phosphate

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / NaHCO₃ / methanol / 1 h / Ambient temperature

2: 95 percent / pyridine / 0.5 h / -20 °C

With sodium hydrogencarbonate; In pyridine; methanol;
DOI:10.1016/S0008-6215(96)00227-3