(3-{[Bis-(2-pyridin-2-yl-ethyl)-amino]-methyl}-2,4,6-trimethyl-benzyl)-bis-(2-pyridin-2-yl-ethyl)-amine

Base Information

• Chemical Name: (3-{[Bis-(2-pyridin-2-yl-ethyl)-amino]-methyl}-2,4,6-trimethyl-benzyl)-bis-(2-pyridin-2-yl-ethyl)-amine
• CAS No.: 110270-92-3
• Molecular Formula: C₃₉H₄₆N₆
• Molecular Weight: 598.834
• Mol file: 110270-92-3.mol

Synonyms:(3-{[Bis-(2-pyridin-2-yl-ethyl)-amino]-methyl}-2,4,6-trimethyl-benzyl)-bis-(2-pyridin-2-yl-ethyl)-amine

Chemical Property of (3-{[Bis-(2-pyridin-2-yl-ethyl)-amino]-methyl}-2,4,6-trimethyl-benzyl)-bis-(2-pyridin-2-yl-ethyl)-amine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (3-{[Bis-(2-pyridin-2-yl-ethyl)-amino]-methyl}-2,4,6-trimethyl-benzyl)-bis-(2-pyridin-2-yl-ethyl)-amine

There total 1 articles about (3-{[Bis-(2-pyridin-2-yl-ethyl)-amino]-methyl}-2,4,6-trimethyl-benzyl)-bis-(2-pyridin-2-yl-ethyl)-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

bis[2-(2-pyridyl)ethyl]amine (15496-36-3) + 2,4-bis(chloromethyl)mesitylene (1585-17-7) → (3-{[Bis-(2-pyridin-2-yl-ethyl)-amino]-methyl}-2,4,6-trimethyl-benzyl)-bis-(2-pyridin-2-yl-ethyl)-amine (110270-92-3)

Guidance literature:

With triethylamine; In ethyl acetate; for 120h; Ambient temperature;

DOI:10.1021/ja00033a024

Reference yield: 82.0%

tetrakis(actonitrile)copper(I) hexafluorophosphate (64443-05-6) + (3-{[Bis-(2-pyridin-2-yl-ethyl)-amino]-methyl}-2,4,6-trimethyl-benzyl)-bis-(2-pyridin-2-yl-ethyl)-amine (110270-92-3) → Cu2((NC5H4CH2CH2)2NCH2)2C6H(CH3)3(2+)*2PF6(1-)*1.25CH2Cl2={Cu2((NC5H4CH2CH2)2NCH2)2C6H(CH3)3}(PF6)2*1.25CH2Cl2

Guidance literature:

In dichloromethane; under Ar; dropwise addn. of diamine in CH2Cl2 to a stirred soln. of copper complex, stirring for 20 min; addn. of Et2O, filtn., ppt. washed with Et2O, drying in vac., elem. anal.;

DOI:10.1021/ja00033a024

Reference yield:

(3-{[Bis-(2-pyridin-2-yl-ethyl)-amino]-methyl}-2,4,6-trimethyl-benzyl)-bis-(2-pyridin-2-yl-ethyl)-amine (110270-92-3) → 2-{[Bis-(2-pyridin-2-yl-ethyl)-amino]-methyl}-3,5,6-trimethyl-phenol (110270-93-4)

Guidance literature:

With oxygen; copper; Yield given. Multistep reaction; 2.) CH₂Cl₂;

DOI:10.1021/ja00254a055

upstream raw materials:

bis[2-(2-pyridyl)ethyl]amine

2,4-bis(chloromethyl)mesitylene

Downstream raw materials:

2-{[Bis-(2-pyridin-2-yl-ethyl)-amino]-methyl}-3,5,6-trimethyl-phenol