[(3-chlorophenyl)sulfonyl]dithioimidocarbonic acid dimethyl ester

Base Information

• Chemical Name: [(3-chlorophenyl)sulfonyl]dithioimidocarbonic acid dimethyl ester
• CAS No.: 93487-82-2
• Molecular Formula: C₉H₁₀ClNO₂S₃
• Molecular Weight: 295.835
• Mol file: 93487-82-2.mol

Synonyms:[(3-chlorophenyl)sulfonyl]dithioimidocarbonic acid dimethyl ester

Chemical Property of [(3-chlorophenyl)sulfonyl]dithioimidocarbonic acid dimethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of [(3-chlorophenyl)sulfonyl]dithioimidocarbonic acid dimethyl ester

There total 2 articles about [(3-chlorophenyl)sulfonyl]dithioimidocarbonic acid dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

carbon disulfide (75-15-0,12122-00-8) + 3-chloro-benzenesulfonamide (17260-71-8) + methyl iodide (74-88-4) → [(3-chlorophenyl)sulfonyl]dithioimidocarbonic acid dimethyl ester (93487-82-2)

Guidance literature:

carbon disulfide; 3-chloro-benzenesulfonamide; With potassium hydroxide; In water; N,N-dimethyl-formamide; Inert atmosphere; Cooling with ice;

methyl iodide; In water; N,N-dimethyl-formamide; at 10 - 20 ℃; Inert atmosphere;

DOI:10.1021/jm200466r

Reference yield:

3-chloro-N-dimercaptomethylene-benzenesulfonamide + methyl iodide (74-88-4) → [(3-chlorophenyl)sulfonyl]dithioimidocarbonic acid dimethyl ester (93487-82-2)

Guidance literature:

In N,N-dimethyl-formamide; for 2h;

DOI:10.1021/jm031019q

Reference yield: 88.0%

4,5-dihydro-1H-pyrazole (109-98-8) + [(3-chlorophenyl)sulfonyl]dithioimidocarbonic acid dimethyl ester (93487-82-2) → N-[(4,5-dihydro-1H-pyrazol-1-yl)-methylsulfanyl-methylidene]-3-chlorobenzenesulfonamide (1337564-61-0)

Guidance literature:

With pyridine; Inert atmosphere; Reflux;

DOI:10.1021/jm200466r

upstream raw materials:

methyl iodide

carbon disulfide

3-chloro-benzenesulfonamide

Downstream raw materials:

N-[(4,5-dihydro-1H-pyrazol-1-yl)-methylsulfanyl-methylidene]-3-chlorobenzenesulfonamide

N-[(3-methyl-4,5-dihydro-1H-pyrazol-1-yl)-methylsulfanyl-methylidene]-3-chlorobenzenesulfonamide

N-[(2,3-diaza-spiro[4.4]non-3-en-2-yl)-methylsulfanyl-methylidene]-3-chlorobenzenesulfonamide

N-[(2,3-diaza-spiro[4.5]dec-3-en-2-yl)-methylsulfanyl-methylidene]-3-chlorobenzenesulfonamide