hydridohydroxo(tetrahydrofuran)bis(triphenylphosphine)ruthenium(II)

Base Information

• Chemical Name: hydridohydroxo(tetrahydrofuran)bis(triphenylphosphine)ruthenium(II)
• CAS No.: 65465-08-9
• Molecular Formula: C₄₀H₄₀O₂P₂Ru
• Molecular Weight: 715.774
• Mol file: 65465-08-9.mol

Synonyms:hydridohydroxo(tetrahydrofuran)bis(triphenylphosphine)ruthenium(II)

Chemical Property of hydridohydroxo(tetrahydrofuran)bis(triphenylphosphine)ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of hydridohydroxo(tetrahydrofuran)bis(triphenylphosphine)ruthenium(II)

There total 4 articles about hydridohydroxo(tetrahydrofuran)bis(triphenylphosphine)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

chlorohydridotris(triphenylphosphine)ruthenium(II) (55102-19-7,879374-40-0,879374-44-4,99944-74-8) → hydridohydroxo(tetrahydrofuran)bis(triphenylphosphine)ruthenium(II) (65465-08-9)

Guidance literature:

With tetrahydrofuran; sodium hydroxide; In tetrahydrofuran; water; Ar-atmosphere; addn. of Ru-complex to 0.5 M aq. NaOH and THF (16 h); volume reduction, pptn. on addn. of excess H2O, collection, recrystn. (THF/ light petroleum); elem. anal.;

DOI:10.1039/DT9770001546

Reference yield:

bis(styrene)bis(triphenylphosphine)ruthenium(0) (68088-93-7) → RuH(OH)(triphenylphosphine)2(tetrahydrofuran) (65465-08-9)

Guidance literature:

With tetrahydrofuran; water; In tetrahydrofuran; water; stirring in THF/water=8:3 (room temp., 10 h); collection, drying (vac.); IR spectroscopy;

DOI:10.1039/DT9780001739

Reference yield:

dihydrido(pyridine)tris(triphenylphosphine)ruthenium(II) (70839-00-8) → RuH(OH)(triphenylphosphine)2(tetrahydrofuran) (65465-08-9)

Guidance literature:

With water; In tetrahydrofuran; stirring in THF contg. H2O (0.5 h); partial evapn., treatment with Et2O (crystn.), collection, drying (vac.);

DOI:10.1039/DT9790001283

upstream raw materials:

bis(styrene)bis(triphenylphosphine)ruthenium⁽⁰⁾

dihydrido(pyridine)tris(triphenylphosphine)ruthenium(II)

chlorohydridotris(triphenylphosphine)ruthenium(II)

Downstream raw materials:

Ru(CO)3(PPh₃)3