Chlorohydrotris(triphenylphosphine)ruthenium

Base Information

• Chemical Name: Chlorohydrotris(triphenylphosphine)ruthenium
• CAS No.: 55102-19-7
• Molecular Formula: C54H46ClP3Ru
• Molecular Weight: 924.404
• European Community (EC) Number: 259-480-7
• Mol file: 55102-19-7.mol

Synonyms:Chlorohydrotris(triphenylphosphine)ruthenium;EINECS 259-480-7;chlororuthenium;cyclohexa-2,4-dien-1-yl(diphenyl)phosphane;triphenylphosphane

Chemical Property of Chlorohydrotris(triphenylphosphine)ruthenium

Chemical Property:

• Vapor Pressure: 1.24E-05mmHg at 25°C
• Melting Point: decomposes at 130℃ [ALD94]
• Boiling Point: 379.9 °C at 760 mmHg
• Flash Point: 193.3 °C
• PSA: 40.77000
• LogP: 7.33840
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Sensitive.: air sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 9
• Exact Mass: 925.162255
• Heavy Atom Count: 59
• Complexity: 504

Purity/Quality:

98%Min ^*data from raw suppliers

Chlorohydridotris(triphenylphosphine)ruthenium(II) toluene adduct, 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 36/37/38-20/21/22
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1C=CC=CC1P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Ru]
• Uses: Starting material to produce high reactive ruthenium metathesis and hydrogenation catalysts.

Technology Process of Chlorohydrotris(triphenylphosphine)ruthenium

There total 33 articles about Chlorohydrotris(triphenylphosphine)ruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + lithium triethylborohydride (22560-16-3) → hydridochlorotris(triphenylphosphine)ruthenium(II) (55102-19-7)

Guidance literature:

In tetrahydrofuran; IR;

DOI:10.1039/c39850001379

Reference yield: 100.0%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + potassium tri-sec-butyl-borohydride → hydridochlorotris(triphenylphosphine)ruthenium(II) (55102-19-7)

Guidance literature:

In tetrahydrofuran; IR;

DOI:10.1039/c39850001379

Reference yield: 99.0%

[Tl(μ-F)3Ru(triphenylphosphine)3] (638163-61-8) + hydrogen (1333-74-0) → hydridochlorotris(triphenylphosphine)ruthenium(II) (55102-19-7)

Guidance literature:

In chloroform-d1; H2 bubbling for 5 min; identified by NMR;

DOI:10.1021/ic034888e

upstream raw materials:

zirconocene dichloride

dihydridotetrakis(triphenylphosphine)ruthenium

tris(triphenylphosphine)ruthenium(II) chloride

bis(cyclopentadienyl)dimethylzirconium(IV)

Downstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II)

(η5-pentadienyl)ruthenium(bis(triphenylphosphine))chloride

K[RuH₃(PPh₃)3]

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