(rhodium(I))Cl[(5H-dibenzo[a,d]cyclohepten-5-yl)2N(methyl)](PPh₃)

Base Information

• Chemical Name: (rhodium(I))Cl[(5H-dibenzo[a,d]cyclohepten-5-yl)2N(methyl)](PPh₃)
• CAS No.: 902153-19-9
• Molecular Formula: C₄₉H₄₀ClNPRh
• Molecular Weight: 812.196
• Mol file: 902153-19-9.mol

Synonyms:(rhodium(I))Cl[(5H-dibenzo[a,d]cyclohepten-5-yl)2N(methyl)](PPh₃)

Chemical Property of (rhodium(I))Cl[(5H-dibenzo[a,d]cyclohepten-5-yl)2N(methyl)](PPh₃)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of (rhodium(I))Cl[(5H-dibenzo[a,d]cyclohepten-5-yl)2N(methyl)](PPh₃)

There total 1 articles about (rhodium(I))Cl[(5H-dibenzo[a,d]cyclohepten-5-yl)2N(methyl)](PPh₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis-(5H-dibenzo[a,d]cyclohepten-5-yl)-methyl-amine (902153-18-8) + chloro(1,5-cyclooctadiene)rhodium(I) dimer + triphenylphosphine (603-35-0) → (rhodium(I))Cl[(5H-dibenzo[a,d]cyclohepten-5-yl)2N(methyl)](PPh3) (902153-19-9)

Guidance literature:

In not given; treatment of (Rh2Cl2(cod)2) with PPh3;

DOI:10.1002/anie.200504382

Reference yield: 94.0%

(rhodium(I))Cl[(5H-dibenzo[a,d]cyclohepten-5-yl)2N(methyl)](PPh3) (902153-19-9) + silver trifluoromethanesulfonate (2923-28-6) → (rhodium(I))[(5H-dibenzo[a,d]cyclohepten-5-yl)2N(methyl)](PPh3) triflate (902153-21-3)

Guidance literature:

In tetrahydrofuran; dichloromethane; byproducts: AgCl; CH2Cl2 and THF added to Rh complex and Ag salt; suspn. stirred at room temp. for 1 h; filtered over celite to remove AgCl; solvents evapd. in vacuo; residue recrystd. from CH2Cl2/hexanes;

DOI:10.1002/anie.200504382

upstream raw materials:

bis-(5H-dibenzo[a,d]cyclohepten-5-yl)-methyl-amine

triphenylphosphine

Downstream raw materials:

(rhodium(I))[(5H-dibenzo[a,d]cyclohepten-5-yl)2N(methyl)](PPh₃) triflate