tert-Butyl cyclohex-2-en-1-ylcarbamate

Base Information

• Chemical Name: tert-Butyl cyclohex-2-en-1-ylcarbamate
• CAS No.: 91230-16-9
• Molecular Formula: C11H19 N O2
• Molecular Weight: 197.277
• Hs Code.: 2924299090
• DSSTox Substance ID: DTXSID30434132
• Nikkaji Number: J491.448A
• Mol file: 91230-16-9.mol

Synonyms:tert-Butyl cyclohex-2-en-1-ylcarbamate;91230-16-9;tert-butyl N-cyclohex-2-en-1-ylcarbamate;tert-Butyl cyclohex-2-enylcarbamate;SCHEMBL19258039;DTXSID30434132;MFCD18206125;tert-Butylcyclohex-2-en-1-ylcarbamate;BS-24847;3-(tert-Butoxycarbonylamino)-1-cyclohexene;CS-0210914;FT-0767014;tert-butyl (S)-cyclohex-2-en-1-ylcarbamate;2-Methyl-2-propanyl 2-cyclohexen-1-ylcarbamate

Chemical Property of tert-Butyl cyclohex-2-en-1-ylcarbamate

Chemical Property:

• PSA: 41.82000
• LogP: 2.82420
• Storage Temp.: 2-8°C
• XLogP3: 2.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 197.141578849
• Heavy Atom Count: 14
• Complexity: 228

Purity/Quality:

99% ^*data from raw suppliers

tert-Butylcyclohex-2-en-1-ylcarbamate 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)OC(=O)NC1CCCC=C1

Technology Process of tert-Butyl cyclohex-2-en-1-ylcarbamate

There total 14 articles about tert-Butyl cyclohex-2-en-1-ylcarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

N-chloro-N-sodio-tert-butylcarbamate (73210-14-7) + 3-phenylselenocyclohexene (83442-20-0) → 3-(N-tert-butoxycarbonylamino)cyclohexene (91230-16-9,153833-66-0)

Guidance literature:

In methanol; at 25 ℃;

Reference yield: 82.0%

tert-butyl N-tosyl-(cyclohex-2-en-1-yl)carbamate (126745-54-8) → 3-(N-tert-butoxycarbonylamino)cyclohexene (91230-16-9,153833-66-0)

Guidance literature:

With sodium naphthalenide; In 1,2-dimethoxyethane; Ambient temperature;

DOI:10.1016/S0040-4039(00)76177-6

Reference yield: 80.0%

(1r,4r)-4-((tert-butoxycarbonyl)amino)cyclohexyl methanesulfonate (177545-89-0) → 3-(N-tert-butoxycarbonylamino)cyclohexene (91230-16-9,153833-66-0) + 7-tert-butoxycarbonyl-7-azabicyclo<2.2.1>heptane (188624-94-4)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran;

DOI:10.1016/j.tetlet.2010.10.079

upstream raw materials:

tert-butyl carbazate

3-phenylselenocyclohexene

tert-butyl N-tosyl-(cyclohex-2-en-1-yl)carbamate

N-chloro-N-sodio-tert-butylcarbamate

Downstream raw materials:

tert-butyl N-methyl-N-(cyclohex-2-en-1-yl)carbamate

C₂HCl₃O₂*C₆H₁₁N

((1S,2R)-2-Hydroxy-cyclohex-3-enyl)-carbamic acid tert-butyl ester

(3aR,7aS)-3-Benzoyl-3a,4,5,7a-tetrahydro-3H-benzooxazol-2-one