Benzene, (2-cyclohexen-1-ylseleno)-

Base Information

• Chemical Name: Benzene, (2-cyclohexen-1-ylseleno)-
• CAS No.: 83442-20-0
• Molecular Formula: C12H14Se
• Molecular Weight: 237.203
• DSSTox Substance ID: DTXSID80471779
• Nikkaji Number: J796.528A
• Mol file: 83442-20-0.mol

Synonyms:Benzene, (2-cyclohexen-1-ylseleno)-;83442-20-0;DTXSID80471779

Chemical Property of Benzene, (2-cyclohexen-1-ylseleno)-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 238.02607
• Heavy Atom Count: 13
• Complexity: 168

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CC=CC(C1)[Se]C2=CC=CC=C2

Technology Process of Benzene, (2-cyclohexen-1-ylseleno)-

There total 14 articles about Benzene, (2-cyclohexen-1-ylseleno)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

Benzeneselenol (645-96-5) + rac-3-bromocyclohexene (1521-51-3,113667-32-6) → 3-phenylselenocyclohexene (83442-20-0)

Guidance literature:

DOI:10.1021/jo00237a052

Reference yield: 91.0%

diphenyl diselenide (1666-13-3) + rac-3-bromocyclohexene (1521-51-3,113667-32-6) → 3-phenylselenocyclohexene (83442-20-0)

Guidance literature:

With indium; In tetrahydrofuran; for 8h; Ambient temperature;

DOI:10.1080/00397919708004807

Reference yield: 87.0%

trimethylstannyl phenyl selenide (4848-71-9) + rac-3-bromocyclohexene (1521-51-3,113667-32-6) → 3-phenylselenocyclohexene (83442-20-0)

Guidance literature:

With {2,6-bis[(phenylseleno)methyl]phenyl}palladium chloride; In tetrahydrofuran; at 60 ℃; for 24h;

DOI:10.1021/jo051266x

upstream raw materials:

rac-3-acetoxycyclohexene

diphenyl diselenide

trans- and cis-1,3-bis(methanesulphonyl)cyclohexane

Benzeneselenol

Downstream raw materials:

3-(N-tert-butoxycarbonylamino)cyclohexene

benzyl (RS)-cyclohex-2-en-1-ylcarbamate

N-cyclohex-2-enyl-4-methyl-benzenesulfonamide